78855-50-2

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 78837-34-0 (2S,3R)-3-Methyl-4-phenylsulfanyl-butan-2-ol 
• 78837-34-0 (+/-)-threo-4-(Phenylthio)-3-methyl-2-butanol 

Downstream Products

• 78822-87-4 (1S,2R,3S,4R)-3-Methyl-1-phenyl-2-phenylsulfanyl-pentane-1,4-diol 
• 78822-88-5 (+/-)-(1R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-1,4-pentadienol 
• 78822-88-5 (+/-)-(1S^*, 3R^*, 4S^*)-3-methyl-1-phenyl-1,4-pentadienol 
• 78822-86-3 (+/-)-(1S^*, 2R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-((S^*)-phenylsulfinyl)-1,4-pentanediol 
• 78822-86-3 (+/-)-(1R^*, 2S^*, 3S^*, 4S^*)-3-methyl-1-phenyl-2-((S^*)-phenylsulfinyl)-1,4-pentanediol 
• 78822-86-3 (+/-)-(1S^*, 2S^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-((R^*)-phenylsulfinyl)-1,4-pentanediol 
• 78822-86-3 (+/-)-(1R^*, 2S^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-((R^*)-phenylsulfinyl)-1,4-pentanediol 
• 78822-86-3 (+/-)-(1R^*, 2R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-((R^*)-phenylsulfinyl)-1,4-pentanediol 
• 78822-86-3 (+/-)-(1S^*, 2R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-((R^*)-phenylsulfinyl)-1,4-pentanediol 
• 78855-54-6 (1S,2R,3R,4R)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol 
• 78855-56-8 (1R,2R,3R,4R)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol 
• 78855-53-5 (1S,2R,3S,4S)-2-((S)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol 
• 78855-55-7 (1R,2R,3S,4S)-2-((S)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol 
• 78822-87-4 (1S,2R,3S,4S)-3-Methyl-1-phenyl-2-phenylsulfanyl-pentane-1,4-diol 

Relevant academic research and scientific papers

STUDIES OF STEREOCHEMICAL CONTROL USING α-LITHIOSULFINYL CARBANIONS

The stereoselectivity in reactions of α-lithiosulfinyl carbanions with aldehydes has been unambiguously established.Steric effects and intramolecular chelation of the associated cation are important factors contributing to the observed outcome.

A Stereoselective Approach to Acyclic Systems via Condensations of α-Lithiosulfinyl Carbanions and Aldehydes

The stereochemical outcome of condensations of α-lithiosulfinyl carbanions with aldehydes is presented, and demonstrates useful methodology for generating 1,2-asymmetry, as well as construction of 1,3-asymmetric relationships in acyclic systems.