78855-57-9Relevant articles and documents
STUDIES OF STEREOCHEMICAL CONTROL USING α-LITHIOSULFINYL CARBANIONS
Williams, David R.,Phillips, James G.,White, Franklin H.,Huffman, John C.
, p. 3003 - 3012 (2007/10/02)
The stereoselectivity in reactions of α-lithiosulfinyl carbanions with aldehydes has been unambiguously established.Steric effects and intramolecular chelation of the associated cation are important factors contributing to the observed outcome.
A Stereoselective Approach to Acyclic Systems via Condensations of α-Lithiosulfinyl Carbanions and Aldehydes
Williams, David R.,Phillips, James G.,Huffman, John C.
, p. 4101 - 4103 (2007/10/02)
The stereochemical outcome of condensations of α-lithiosulfinyl carbanions with aldehydes is presented, and demonstrates useful methodology for generating 1,2-asymmetry, as well as construction of 1,3-asymmetric relationships in acyclic systems.