78964-28-0Relevant articles and documents
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Joseph-Nathan,P.,Hernandez,J.
, p. 669 (1982)
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Synthesis of (±)-heliannuol D based on platinum catalyzed regioselective addition of arylboronic acids to allenes
Osaka, Mayu,Kanematsu, Makoto,Yoshida, Masahiro,Shishido, Kozo
experimental part, p. 1003 - 1012 (2010/10/19)
An alternative total synthesis of (±)-heliannuol D has been achieved in 13 steps and 6.9% overall yield from the arylboronic acid 9. The synthesis applies the previously developed regiocontrolled addition of arylboronic acids to alienes using a platinum catalyst to install the C5 carbon chain on the aryl ring.
Reaction of methyl 4,5-epoxy-(2E)-pentenoate with arenes. II. Application to the synthesis of(±)-curcudiol, (±)-curcuphenol, (±)-curcuhydroquinone, and(±)-curcuquinone
Ono,Yamamoto,Akita
, p. 553 - 558 (2007/10/02)
Four bisabolane sesquiterpenes, (±)-curcudiol (2), (±)-curcuphenol (3), (±)-curcuhydroquinone (5) and (±)-curcuquinone (6), were synthesized based on the reaction of methyl 4,5-epoxy-(2E)-pentenoate (1) with methoxytoluenes in the presence of boron trifluoride etherate.