78999-89-0

Basic information

• Product Name: N-(diphenylmethylene)-1-(4-methoxyphenyl)methanamine
• Synonyms: N-(diphenylmethylene)-1-(4-methoxyphenyl)methanamine
• CAS NO: 78999-89-0
• Molecular Weight: 301.388
• Mol File: 78999-89-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(diphenylmethylene)-1-(4-methoxyphenyl)methanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(diphenylmethylene)-1-(4-methoxyphenyl)methanamine(78999-89-0)
• EPA Substance Registry System: N-(diphenylmethylene)-1-(4-methoxyphenyl)methanamine(78999-89-0)

Safety Data

• Hazardous Substances Data: 78999-89-0(Hazardous Substances Data)

Upstream product

• 91-00-9 Benzhydrylamine 
• 123-11-5 4-methoxy-benzaldehyde 
• 119-61-9 benzophenone 
• 2393-23-9 4-methoxy-benzylamine 
• 805316-34-1 (E)-N-(4-methoxybenzylidene)-1,1-diphenylmethanamine 
• 122-04-3 4-nitro-benzoyl chloride 

Downstream Products

• 60996-87-4 (diphenylmethyl)[(4-methoxyphenyl)methyl]amine 
• 69939-39-5 N-(diphenylmethylene)-1-(p-methoxyphenyl)-1-phenylmethanamine 
• 5267-46-9 4-methoxy-benzhydrylamine; hydrochloride 
• 108893-53-4 4-benzoyloxy-3-(p-methoxyphenyl)-1,4,4-triphenyl-2-azabuta-1,3-diene 

Relevant articles and documents

Visible-Light-Mediated Umpolung Reactivity of Imines: Ketimine Reductions with Cy2NMe and Water

A novel carbanionic reactivity of imines mediated by photoredox catalysis is demonstrated. The umpolung imine reactivity is exemplified by proton abstraction from water as a key step in the reduction of benzophenone ketimines to amines (up to 98% yield). Deuterium is introduced into amines efficiently using D2O as an inexpensive deuterium source (≥95% D ratio). The mechanism of this unusual transformation is probed.

Aroylation of Carbanions Derived from N-(Diphenylmethyl)arylmethanimines. A Synthesis of 4-Aroyloxy-2-azabuta-1,3-dienes

The acylation of carbanions derived from N-(diphenylmethyl)arylmethanimines using aroyl chlorides, allows the preparation of a new type of substituted 2-azabuta-1,3-dienes in which the imino group is conjugated with an enol ester.The reaction is quite general and facilitates the preparation of a wide range of 2-azadienes with electron-donating and electron-withdrawing groups on the phenyl rings.The site selectivity for the attack of the electrophile on the aza-allyl anion can be controlled by the substituents on the carbanion and on the hardness of the electrophile.