79032-16-9Relevant articles and documents
2-Halogeno-1,3-dithiane 1,3-dioxide: a diastereoselective carbonyl anion equivalent in reactions with aldehydes
Aggarwal, Varinder K.,Boccardo, Giorgio,Worrall, Julia M.,Adams, Harry,Alexander, Rikki
, p. 11 - 20 (2007/10/03)
The metal anions of 2-halogeno-1,3-dithiane trans-1,3-dioxide react diastereoselectively with aldehydes.The scope and limitations of this reaction have been studied through variations in the metal counter-ion, halogen, aldehyde and reaction temperature, w
Electrosynthesis of 1,2-Dithiolane 1-Oxides from Substituted 1,3-Dithianes
Glass, Richard S.,Petsom, Amorn,Wilson, George S.,Martinez, Roberto,Juaristi, Eusebio
, p. 4337 - 4342 (2007/10/02)
Controlled potential oxidation of variety of 5-substituted 2-tert-butyl-1,3-dithianes in wet acetonitrile, using an undivided electrochemical cell, provide 4-substituted 1,2-dithiolane 1-oxides selectively and in good yields.Adsorption to the electrode surface of the platinum anode, rendering it passive in the electrolysis of these sulfur-containing compounds is a solvable problem.Although acid-sensitive O-trimethylsilyl ethers are cleaved under the reaction conditions, O-tert-butyldimethylsilyl ethers only suffer cleavage to a modest extent, and an ethylene ketal moiety suffers little, if any, cleavage.