79039-69-3

Upstream product

• 403-42-9 1-(4-fluorophenyl)ethanone 
• 719-59-5 5-chloro-2-aminobenzophenone 
• 104-15-4 toluene-4-sulfonic acid 
• 3158-99-4 1-phenyl-1-(2-amino-5-chlorophenyl)ethylene 
• 106-47-8 4-chloro-aniline 
• 536-74-3 phenylacetylene 
• 1765-93-1 4-fluoroboronic acid 
• 73862-39-2 6-chloro-4-phenylquinoline-2(1H)-thione 
• 329-79-3 1-(4-fluorophenyl)ethanone oxime 

Downstream Products

• 913331-23-4 Ir(acetylacetonato)(6-chloro-2-(4-fluorophenyl)-4-phenylquinoline(-1H))2 

Relevant academic research and scientific papers

Palladium-Catalyzed/Copper-Mediated Desulfurization and Aryl- ation of Quinoline-2-(1 H)-thione for Rapid Access to Quinoline Derivatives

An efficient method for carbon-carbon bond formation is described. The process employs the palladium-catalyzed and copper-mediated cross-coupling of quinoline-2-(1 H)-thiones with arylboronic acids or alkynes through C-S bond cleavage without an inert atm

Highly efficient iridium(III) complexes with diphenylquinoline ligands for organic light-emitting diodes: Synthesis and effect of fluorinated substitutes on electrochemistry, photophysics and electroluminescence

A series of novel cyclometalated iridium(III) complexes bearing 2,4-diphenylquinoline ligands with fluorinated substituent were prepared and characterized by elemental analysis, NMR and mass spectroscopy. The cyclic voltammetry, absorption, emission and e

Method of preparation of polyquinolines

New polyquinoline polymers are provided, as well as new methods for preparing the polyquinoline polymers using a novel combination of monomers. The polyquinoline polymers comprise repeat units comprising at least one quinoline nucleus and at least one ether linkage and having as end groups either fluoro groups or hydroxy groups or a combination of fluoro and hydroxy groups. The polymers are formed by providing a monomer comprising two fluoro groups, where each such fluoro group is activated by a quinoline nucleus, a diol monomer provided in the form of its bis-oxide salt, or in the presence of a base capable of deprotonating the diol and reacting the difluoro and diol monomers together in a dipolar solvent to form the polyquinoline polymer. In an alternative embodiment, the polyquinoline polymers of the present invention are formed by reacting a fluoro hydroxy monomer comprising a quinoline nucleus containing one activated fluoro group and one hydroxy group in the presence of a base and a dipolar solvent to form said polymer. In yet another alternative embodiment, the polyquinoline polymer is formed by providing a monomer which comprises a quinoline nucleus containing one activated fluoro group and one hydroxy group and treating the monomer with a base to form an oxide salt and reacting the monomer salt in a dipolar solvent to form said polymer.

Nickel phosphate catalysts

Methods for coupling aryl halides or aryl sulfonates to produce biaryls or polyaryls using novel nickel phosphite catalysts are provided.

Preparation of 2,4-Diarylquinolines and Substituted Dihydrobenzacridines by the Condensation of Certain C(α),O-Dilithiooximes with 2-Aminobenzophenones

C(α),O-Dilithiooximes were prepared in an excess of lithium diisopropylamide and condensed with several 2-aminobenzophenones, followed by acid hydrolysis of the oximes to the ketones, which then underwent cyclodehydration to give substituted quinolines or dihydrobenzacridines.