79047-38-4

Upstream product

• 603-35-0 triphenylphosphine 

Downstream Products

• 64276-62-6 4-phenyl-1H-pyrrole-3-carboxylic acid ethyl ester 
• 100485-24-3 trans-bis(dimethylglyoximato)iron(tosylmethyl isocyanide)(1-methylimidazole) 
• 102777-48-0 (2,3,7,8,12,13,17,18-octaethyl-5-aza-porphyrinato)bis(tosyl methylisocyanide)iron(II) 
• 100485-32-3 trans-bis(dimethylglyoximato)iron(tributyl phosphite)(tosylmethyl isocyanide) 
• 100485-28-7 trans-bis(dimethylglyoximato)iron(tributylphosphine)(tosylmethyl isocyanide) 
• 41969-71-5 diethyl pyrrole-3,4-dicarboxylate 
• 603-35-0 triphenylphosphine 
• 70647-26-6 3-nitro-4-phenyl-1H-pyrrole 

Relevant academic research and scientific papers

Axial ligand substitution reactions of ruthenium(II) dimethylglyoxime complexes

Kinetics of ligand substitution reactions of six-coordinated Ru(II) macrocyclil complexes of the following type have been investigated: (T)Ru(DMGH)2(L) + X -> (T)Ru(DMGH)2(X) + L where T and L are either both triphenylphosphine ligands or methylimidazole and triphenylphosphine ligands, respectively.The nucleophile X is either MeIm, Im, py, pip, P(OBu)3 or Timc.In all cases, with the exception of Timic as a nucleophile, the reaction mechanism is strictly dissociative (D).The reaction proceeds through the formation of a five-coordinate intermediate which possess little or no ability to discriminate between different nucleophiles.In the case of Tmic, the rate data can be fitted by a dissociative Id or a Associative Ia interchange mechanism.