79054-58-3Relevant academic research and scientific papers
Unexpected reaction of N,N-dichloroarenesulfonamides with divinyl sulfide: Formation of N-[2-chloro- and N-[2,2-dichloro-1-(arylsulfonylamino)ethyl] arenesulfonamides
Rozentsveig, Igor B.,Rozentsveig, Gulnur N.,Levkovskaya, Galina G.,Amosova, Svetlana V.,Potapov, Vladimir A.,Chernyshev, Kirill A.,Tretyakov, Eugene V.,Romanenko, Galina V.
experimental part, p. 181 - 192 (2011/12/05)
Reaction of N,N-dichloroarenesulfonamides with divinyl sulfide was accompanied by cleavage of divinyl sulfide moiety and resulted in unexpected N-[2-chloro- and N-[2,2-dichloro-1-(arylsulfonylamino)ethyl]arenesulfonamides as final products. Possible react
N,N-DICHLOROARENESULFONAMIDES IN REACTION WITH 1,2-DICHLOROETHYLENE
Mirskova, A. N.,Drozdova, T. I.,Levkovskaya, G. G.,Kalikhman, I. D.,Voronkov, M. G.
, p. 1129 - 1135 (2007/10/02)
The reaction of N,N-dichloroarenesulfonamides with cis- and trans-1,2-dichloroethylene under the conditions of free-radical initiation lead to the formation of the N-arylsulfonylimines of dichloroacetaldehyde and the products from their further transformation, i.e., 2,2-dichloro-1,1-di(arylsulfonylamino)ethanes.The arylsulfonylimines of chloral, arenesulfonamides, trichloroethylene, and the products from chlorination of 1,2-dichloroethylene are formed as side products.
