79063-97-1Relevant academic research and scientific papers
The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings
Kawana, Masajiro,Kuzuhara, Hiroyoshi,Emoto, Sakae
, p. 1492 - 1504 (2007/10/02)
The anomerization of methyl glycofuranoside derivatives with methylmagnesium iodide or t-butylmagnesium bromide occurred in a one-way manner.For example, methyl 5-O-benzyl-β-D-ribofuranoside (3β) was converted into the corresponding α-anomer (3α) in a 95p
