79063-96-0

Basic information

• Product Name: 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose
• Synonyms: 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose
• CAS NO: 79063-96-0
• Molecular Weight: 410.51
• Mol File: 79063-96-0.mol

Chemical Properties

• CAS DataBase Reference: 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose(79063-96-0)
• EPA Substance Registry System: 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose(79063-96-0)

Safety Data

• Hazardous Substances Data: 79063-96-0(Hazardous Substances Data)

Upstream product

• 22250-06-2 1,2-O-Cyclohexylidene-α-D-xylofuranose 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 

Downstream Products

• 16054-77-6 3,5-di-O-benzyl-D-xylofuranose 
• 645403-02-7 3-O-benzyl-1,2-O-cyclohexilidene-α-D-xylofuranose 
• 79083-39-9 1-O-methyl 3,5-di-O-benzyl β(D)xylo-pentoaldofuranose 
• 79083-38-8 1-O-methyl 3,5-di-O-benzyl α(D)xylo-pentoaldofuranose 
• 79063-91-5 (2R,3S,4S)-1,3-Bis-benzyloxy-5-methoxy-hexane-2,4-diol 
• 79063-97-1 (R)-3,5-Bis-benzyloxy-4-hydroxy-1-methoxy-pentan-2-one 
• 18449-76-8 methyl α-D-lyxopyranoside 
• 159148-13-7 Methyl 3,5-di-O-benzyl-α-D-lyxofuranoside 

Relevant articles and documents

Enantiodivergent synthesis of cytotoxic styryl lactones from d-xylose. The first total synthesis of (+)- and (-)-crassalactone C

Enantiodivergent total syntheses of both (+)- and (-)-enantiomers of goniofufurone, 7-epi-goniofufurone and crassalactone C have been accomplished starting from d-xylose. The key steps of the synthesis of 7-epi-(+)-goniofufurone were a stereo-selective ad

Synthesis and antiproliferative activity of unnatural enantiomers of 7-epi-goniofufurone and crassalactone C

A facile synthesis of 7-epi-(-)-goniofufurone as well as the first synthesis of (-)-crassalactone C was achieved starting from d-xylose. A comparison of their in vitro antitumour activities with those observed for the corresponding naturally occurring enantiomers was provided.

Conversion of D-xylose to protected D-lyxose derivatives and to D-lyxose, via the corresponding 1,2-anhydride

Acid hydrolysis of 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose gave the corresponding lactol, which was subsequently converted to the 3,5-di-O-benzyl-2-O-mesyl-D-xylofuranose. This compound readily reacted with sodium methoxide, sodium benzylate or sodium hydroxide (presumably via the corresponding 1,2-anhydride) to give the protected D-lyxofuranosides. These compounds were finally converted to methyl α-D-lyxopyranoside or to D-lyxose. Copyright (C) 1999 Elsevier Science Ltd.

The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings

The anomerization of methyl glycofuranoside derivatives with methylmagnesium iodide or t-butylmagnesium bromide occurred in a one-way manner.For example, methyl 5-O-benzyl-β-D-ribofuranoside (3β) was converted into the corresponding α-anomer (3α) in a 95p