79083-39-9Relevant academic research and scientific papers
Synthesis, conformational analysis and biological studies of cyclic cationic antimicrobial peptides containing sugar amino acids
Chakraborty, Tushar Kanti,Koley, Dipankar,Ravi, Rapolu,Krishnakumari, Viswanatha,Nagaraj, Ramakrishnan,Kunwar, Ajit Chand
experimental part, p. 8731 - 8744 (2009/04/11)
(Chemical Equation Presented) Sugar amino acid based 24-membered macrocyclic C2-symmetric cationic peptides were designed and synthesized. The cationic group was introduced in the sugar amino acids. The conformation of these cyclic compounds was ascertain
An epoxide derived from D-glucose as the key intermediate for penaresidine and sphingolipids synthesis
Beauhaire, Josiane,Ducrot, Paul-Henri
, p. 2443 - 2456 (2007/10/03)
A multigram-scale synthesis of 3R,4R,5R 3,5-dibenzyloxy-4-p- methoxybenzyl-1,2-epoxypentane and its use as intermediate for sphingolipids, penazeridine and penazetidine synthesis are described.
Synthesis and glycosidic reaction of 1,2-anhydromanno-, lyxo-, gluco-, and xylofuranose perbenzyl ethers
Du, Yuguo,Kong, Fanzuo
, p. 797 - 817 (2007/10/03)
Stereospecific synthesis of 1,2-anhydromanno-, lyxo-, gluco-, and xylofuranose perbenzyl ethers was successfully achieved via intramolecular SN2 reaction of the corresponding C-1 alkoxide with C-2 bearing tosyloxy group. The key intermediates, furanose 2-sulfonates, were prepared from the corresponding 1,2-diols and tosyl chloride under phase transfer conditions in good yields. Condensation of the anhydro sugars with 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose or N-benzyloxycarbonyl L-serine methyl ester in the absence of catalyst gave 1,2-trans-linked glycofuranosides in high yield.
A facile synthesis of 1,2-anhydroglycofuranose benzyl ethers
Yuguo, Du,Fanzuo, Kong
, p. 427 - 430 (2007/10/02)
The synthesis of 1,2-anhydromanno-, -lyxo-, -gluco-, and -xylofuranose benzyl ethers was successfully achieved via intramolecular S(N)2 reaction of the corresponding C-1 alkoxide with C-2 bearing tosyloxy group. The key intermediates, furanose 2-sulfonate
The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings
Kawana, Masajiro,Kuzuhara, Hiroyoshi,Emoto, Sakae
, p. 1492 - 1504 (2007/10/02)
The anomerization of methyl glycofuranoside derivatives with methylmagnesium iodide or t-butylmagnesium bromide occurred in a one-way manner.For example, methyl 5-O-benzyl-β-D-ribofuranoside (3β) was converted into the corresponding α-anomer (3α) in a 95p
