79080-88-9Relevant academic research and scientific papers
C-Glycoside D-galacturonates suitable as glycosyl acceptors for the synthesis of allyl C-homo- and rhamno-galacturonan modules
Farouk, Mahmoud,Michalik, Dirk,Villinger, Alexander,Vogel, Christian
, p. 389 - 407 (2013/05/22)
Methyl 2,3-di-O-benzyl-1-deoxy-1-(prop-2-enyl)-α-D- galactopyranuronate and benzyl 2,3-di-Obenzyl- 1-deoxy-1-(prop-2-enyl)-α- D-galactopyranuronate were prepared as glycosyl acceptors. The glycosyl donors benzyl 4-O-acetyl-2,3-di-O-benzyl-1-(trichloroacet
Studies towards a conjugate vaccine for anthrax: Synthesis of the tetrasaccharide side chain of the Bacillus anthracis exosporium
Adamo, Roberto,Saksena, Rina,Kovac, Pavol
, p. 1075 - 1089 (2007/10/03)
The first synthesis of β-L-glycoside 17 of the tetrasaccharide β-Ant-(1 → 3)-α-L-Rhap-(1 → 3)-α-L-Rhap-(1 → 2)-L-Rhap is described (Schemes 1-3). Its spacer can be functionalized to make it amenable to conjugation to proteins by different conjugation meth
A new method for the stereoselective synthesis of α- and β-glycosylamines using the Burgess reagent
Nicolaou,Snyder, Scott A.,Nalbandian, Annie Z.,Longbottom, Deborah A.
, p. 6234 - 6235 (2007/10/03)
Although glycosylamines constitute an important group of carbohydrates from the standpoint of biology and medicine, methods for their synthesis typically lack substrate generality and/or result in variable stereoselectivity, especially in complex contexts
Synthesis, conformational analysis, and the glycosidic coupling reaction of substituted 2,7-dioxabicyclo[4.1.0]heptanes: 1,2-anhydro-3,4-di-O-benzyl-β-L- and β-D-rhamnopyranoses
Chen,Kong,Cao
, p. 107 - 117 (2007/10/02)
1,2-Anhydro-3,4-di-O-benzyl-α-L-rhamnopyranose was synthesized from L-rhamnose, while the D-enantiomer was synthesized from methyl 6-deoxy-2,3-O-isopropylidene-α-D-mannopyranoside. For both of the syntheses, the key intermediates were 2-O-acetyl-3,4-di-O-
CARBOHYDRATE COMPONENTS OF FLAVONOL TRIAOSIDES: A CONVENIENT SYNTHESIS OF O-α-L-RHAMNOPYRANOSYL-(1->3)-O-α-L-RHAMNOPYRANOSYL-(1->6)-D-GALACTOSE AND-O-α-RHAMNOPYRANOSYL-(1->6)-D-GALACTOSE
Liptak, Andras,Nanasi, Pal,Neszmenyi, Andras,Riess-Maurer, Ingrid,Wagner, Hildebert
, p. 43 - 52 (2007/10/02)
Condensation of 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose (1) with 2,4-di-O-acetyl-3-O-(2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl bromide (2), followed by subsequent removal of the isopropylidene and acetyl groups from the product,
Synthesis of β-D-Mannopyranosides and β-L-Rhamnopyranosides by Glycosidation at C-1
Srivastava, Vinai K.,Schuerch, Conrad
, p. 1121 - 1126 (2007/10/02)
A stereoselective synthesis of β-D-mannopyranosides and β-L-rhamnopyranosides has been achieved by glycosidation at C-1.Treatment of the 1-O-tosyl derivative 2 with 1 equiv of methanol in acetonitrile gave methyl 3,4,6-tri-O-benzyl-2-O-(methylsulfonyl)-β-
