79131-71-8

Upstream product

• 115534-43-5 N-<8-(dichloromethyl)-3a,4,8,9,9a,9b-hexahydro-5-hydroxy-2,2,8-trimethyl-6H-1,3-dioxolo<4,5-f><2>benzopyran-9-yl>-2-(trimethylsilyl)ethanesulfonamide 
• 115534-35-5 endo-(+/-)-N-(3-oxo-2-oxabicyclo<3.3.1>non-6-en-4-yl)-2-(trimethylsilyl)ethanesulfonamide 
• 115534-36-6 2-Trimethylsilanyl-ethanesulfonic acid ((1R,6R,9R)-8-oxo-3,7-dioxa-tricyclo[4.3.1.0^2,4]dec-9-yl)-amide 
• 115534-37-7 2-Trimethylsilanyl-ethanesulfonic acid ((1S,4S,5S,6S,7S)-6,7-dihydroxy-3-oxo-2-oxa-bicyclo[3.3.1]non-4-yl)-amide 
• 115534-39-9 N-<1-(hexahydro-6-hydroxy-2,2-dimethyl-1,3-benzodioxol-4-yl)-2-oxopropyl>-2-(trimethylsilyl)ethanesulfonamide 
• 126423-75-4 (S)-N-Methoxy-N-methyl-2-((1S,2S,3S,5S)-2,3,5-trihydroxy-cyclohexyl)-2-(2-trimethylsilanyl-ethanesulfonylamino)-acetamide 
• 115534-40-2 N-<3,3-dichloro-1-(hexahydro-6-hydroxy-2,2-dimethyl-1,3-benzodioxol-4-yl)-2-hydroxy-2-methylpropyl>-2-(trimethylsilyl)ethanesulfonamide 
• 126423-76-5 (S)-2-((3aS,4S,6S,7aS)-6-Hydroxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl)-N-methoxy-N-methyl-2-(2-trimethylsilanyl-ethanesulfonylamino)-acetamide 
• 115534-41-3 N-<3,3-dichloro-1-(hexahydro-2,2-dimethyl-6-oxo-1,3-benzodioxol-4-yl)-2-methylpropyl>-2-(trimethylsilyl)ethanesulfonamide 
• 115534-42-4 (4R,5R)-5-Dichloromethyl-4-((3aR,4R,7aR)-2,2-dimethyl-6-oxo-hexahydro-benzo[1,3]dioxol-4-yl)-5-methyl-3-(2-trimethylsilanyl-ethanesulfonyl)-oxazolidin-2-one 
• 115534-38-8 (R)-2-[(3aR,4R,6R,7aR)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl]-N-methoxy-N-methyl-2-(2-trimethylsilanyl-ethanesulfonylamino)-acetamide 
• 99457-40-6 (1S,5S)-2-Oxa-bicyclo[3.3.1]non-6-ene-3,4-dione 

Downstream Products

• 115559-70-1 [(S)-1-((3S,4R,4aR,5R,6R)-3-Dichloromethyl-5,6,8-trihydroxy-3-methyl-1-oxo-3,4,4a,5,6,7-hexahydro-1H-isochromen-4-ylcarbamoyl)-ethyl]-carbamic acid benzyl ester 
• 115534-44-6 [(S)-1-((3R,4S,4aS,5S,6S)-3-Dichloromethyl-5,6,8-trihydroxy-3-methyl-1-oxo-3,4,4a,5,6,7-hexahydro-1H-isochromen-4-ylcarbamoyl)-ethyl]-carbamic acid benzyl ester 
• 72615-20-4 (-)-Bactobolin 

Relevant academic research and scientific papers

Stereoselective Total Synthesis of the Antitumor Antibiotic (-)-Bactobolin

The first total synthesis of the biologically active microbial metabolite bactobolin (2) has been achieved.An efficient, stereoselective route to 2 in 16 steps from previously prepared α-keto lactone 3 is outlined.