791854-75-6

Upstream product

• 132610-89-0 (-)-(R)-2-methyl-5-isopropenyl-3-phenylcyclohex-2-en-1-one 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 100-39-0 benzyl bromide 
• 132696-81-2 (-)-(1S,4S,8R)-1,8-Dimethyl-8-methoxy-6-phenylbicyclo<2.2.2>oct-5-en-2-one 

Downstream Products

• 791855-01-1 (1S,4R,8R)-3-benzyl-8-methoxy-1,8-dimethyl-6-phenylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 

Relevant academic research and scientific papers

Chiral [2.2.2] dienes as ligands for Rh(I) in conjugate additions of boronic acids to a wide range of acceptors

We document a series of investigations that led to new substituted [2.2.2]-diene ligands which display high selectivity in Rh(I)-catalyzed conjugate addition reactions to substrates not previously examined with diene ligands. Moreover, we disclose an unexpected, interesting effect that results from the introduction of a third C=C onto the ligand scaffold (cf. 1).