79239-16-0Relevant academic research and scientific papers
ONE-ELECTRON OXIDATION OF ANISPINACOLONE WITH DIAROYL PEROXIDES: MECHANISTIC CHANGEOVER OF THE PEROXIDE FUNCTION FROM RADICAL TO MOLECULAR OXIDATION
Okamoto, Kunio,Takeuchi, Ken'ichi,Murai, Osamu,Matsui, Shin,Inoue, Takeshi,Kitagawa, Toshikazu
, p. 2785 - 2788 (1981)
Oxidative cleavage of anispinacolone (An3C*CO*An, An=p-methoxyphenyl) with diaroyl peroxides proceeds by electron-transfer mechanism, which starts with rate-determining decomposition of the peroxide, unimolecular for dibenzoyl and bimolecular for bis(3,5-
