ONE-ELECTRON OXIDATION OF ANISPINACOLONE WITH DIAROYL PEROXIDES: MECHANISTIC CHANGEOVER OF THE PEROXIDE FUNCTION FROM RADICAL TO MOLECULAR OXIDATION

DOI: 10.1016/S0040-4039(01)90552-0

Source and publish data:

Tetrahedron Letters p. 2785 - 2788 (1981)

Update date:2022-08-03

Topics:

Authors:

Okamoto, Kunio

Takeuchi, Ken'ichi

Murai, Osamu

Matsui, Shin

Inoue, Takeshi

Kitagawa, Toshikazu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90552-0

Oxidative cleavage of anispinacolone (An3C*CO*An, An=p-methoxyphenyl) with diaroyl peroxides proceeds by electron-transfer mechanism, which starts with rate-determining decomposition of the peroxide, unimolecular for dibenzoyl and bimolecular for bis(3,5-

Full text of DOI:10.1016/S0040-4039(01)90552-0

Products guided by the article

Product name:4-methoxybenzoic 3,5-dinitrobenzoic anhydride

Cas No:79239-16-0

R&D Labs maybe for 79239-16-0

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
Xiamen Yunfan Biotech Co., Ltd.

Contact:0592-7828678-#

Address:Xiamen

Relevant to this article

Gram-scale preparation of dialkylideneacetones through Ca(OH)₂-catalyzed Claisen-Schmidt condensation in dilute aqueous EtOH

Doi:10.1016/j.cclet.2018.01.035
(2018)
Lipase-mediated resolution of indene bromohydrin

Doi:10.1055/s-1997-1226
(1997)
cis-1,2-Bis(9-anthryl)ethylene: Preparation and Photochemical Properties

Doi:10.1021/jo00339a039
(1981)
Isomeric phenylthioimidazo[1,2-a]pyridines as anthelmintics

Doi:10.1021/jm00144a022
(1981)
Selective and sensitive fluorescent sensors for metal ions based on manipulation of side-chain compositions of poly(p-phenyleneethynylene)s

Doi:10.1021/ac049163m
(2004)
A NOVEL SYNTHESIS OF 3-FLUOROPHENYLALANINE and SOME of ITS DERIVATIVES

Doi:10.1016/S0022-1139(00)82305-2
(1981)

Article Doi