ONE-ELECTRON OXIDATION OF ANISPINACOLONE WITH DIAROYL PEROXIDES: MECHANISTIC CHANGEOVER OF THE PEROXIDE FUNCTION FROM RADICAL TO MOLECULAR OXIDATION

DOI: 10.1016/S0040-4039(01)90552-0

Source and publish data:

Tetrahedron Letters p. 2785 - 2788 (1981)

Update date:2022-08-03

Topics:

Authors:

Okamoto, Kunio

Takeuchi, Ken'ichi

Murai, Osamu

Matsui, Shin

Inoue, Takeshi

Kitagawa, Toshikazu

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Article abstract of DOI:10.1016/S0040-4039(01)90552-0

Oxidative cleavage of anispinacolone (An3C*CO*An, An=p-methoxyphenyl) with diaroyl peroxides proceeds by electron-transfer mechanism, which starts with rate-determining decomposition of the peroxide, unimolecular for dibenzoyl and bimolecular for bis(3,5-

Full text of DOI:10.1016/S0040-4039(01)90552-0

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