79258-05-2

Basic information

• Product Name: 3,6,6-triphenyl-1,2,4-trioxane
• Synonyms: 3,6,6-triphenyl-1,2,4-trioxane
• CAS NO: 79258-05-2
• Molecular Weight: 318.372
• Mol File: 79258-05-2.mol

Chemical Properties

• CAS DataBase Reference: 3,6,6-triphenyl-1,2,4-trioxane(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6,6-triphenyl-1,2,4-trioxane(79258-05-2)
• EPA Substance Registry System: 3,6,6-triphenyl-1,2,4-trioxane(79258-05-2)

Safety Data

• Hazardous Substances Data: 79258-05-2(Hazardous Substances Data)

Upstream product

• 882-59-7 1,1-diphenyloxirane 
• 21143-47-5 α,α'-dioxydibenzyl alcohol 

Downstream Products

• 4217-62-3 1,1-diphenyl-1,2-ethanediol 
• 121744-32-9 Benzoic acid 2-hydroxy-2,2-diphenyl-ethyl ester 
• 65-85-0 benzoic acid 
• 93-89-0 benzoic acid ethyl ester 

Relevant articles and documents

Synthesis and Reaction of 1,2,4-Trioxanes

The peroxides (1a-e) and epoxides (2a-g) in methylene dichloride were treated with tungsten (VI) oxide and then with catalitic amounts of chlorosulphonic acid to give the corresponding 1,2,4-trioxanes (3a-r) in 10-63percent yield.The mode of decomposition of the 1,2,4-trioxanes was studied by treating a number with the following reagents: triethylamine, sodium ethoxide, lithium di-isopropylamide, Grignard and lithium reagents, lithium aluminium hydride, anthrylsodium, triphenylphosphine, and titanium tetrachloride.

Synthesis of 1,2,4-Trioxans

The reaction of a mixture of α-hydroxydecyl hydroperoxide and epoxides in the presence of tungstic anhydride and catalytic amounts of chlorosulphonic acid gave the corresponding 1,2,4-trioxans in 7 - 63 percent yield.