79310-02-4Relevant academic research and scientific papers
New heterocyclic precursors for thermal generation of reactive, electron-rich 1,2-diaza-1,3-butadienes
Boeckman Jr., Robert K.,Ge, Ping,Reed, Jessica E.
, p. 3647 - 3650 (2007/10/03)
Figure presented The preparation and thermolysis of new stable heterocyclic precursors of 1,2-diaza-1,3-butadienes is described. The resulting reactive diazadienes are trapped in situ with N-phenyldiazamaleimide. The effect of precursor structure on the temperature at which the diazadienes are generated is discussed.
Cycloaddition Reactions of Sulphines and Thiones with Azoalkenes
Bonini, Bianca F.,Maccagnani, Gaetano,Mazzanti, Germana,Rosini, Goffredo,Foresti, Elisabetta
, p. 2322 - 2327 (2007/10/02)
Fluorenethione S-oxide undergoes (2+4) cycloadditions with azoalkenes to yield 2H-1,2,3-thiadiazine 1-oxides together with a small amount of the regioisomeric 6H-1,3,4-thiadiazine 1-oxides.Fluorenethione, with azoalkenes, undergoes (2+4) regiospecific cycloaddition reactions leading to the formation of 6H-1,3,4-thiadiazine derivatives.Diarylsulphines and diarylthiones fail to react with azoalkenes.
