79311-12-9Relevant academic research and scientific papers
PALLADIUM-CATALYZED REGIOSELECTIVE REACTIONS OF α-ACETOXY-β,γ-UNSATURATED NITRILES AND γ-ACETOXY-α,β-UNSATURATED ESTER WITH NUCLEOPHILES
Tsuji, Jiro,Ueno, Hiroaki,Kobayashi, Yuichi,Okumoto, Hiroshi
, p. 2573 - 2574 (1981)
α-Acetoxy-β,γ-unsaturated nitriles react at room temperature with malonates and acetoacetates in the presence of palladium-phosphine complexes as a catalyst to give γ-substituted α,β-unsaturated nitriles selectively.Also γ-acetoxy-α,β-unsaturated ester wa
