793653-17-5Relevant academic research and scientific papers
Synthesis of sulfur-rich polymers: Copolymerization of episulfide with carbon disulfide by using [PPN]Cl/(salph)Cr(III)Cl system
Nakano, Koji,Tatsumi, Go,Nozaki, Kyoko
, p. 15116 - 15117 (2007)
The completely alternating copolymerization of propylene sulfide with carbon disulfide was first achieved. Copolymerization by using anionic initiator [Ph3P=N=PPh3]Cl gave poly(propylene trithiocarbonate). The addition of chromium complex was found to accelerate the copolymerization. The obtained copolymer has a completely alternating structure with high regioregularity and showed large refractive index of 1.781-1.782. Copyright
