Journal of the American Chemical Society p. 15116 - 15117 (2007)
Update date:2022-08-05
Topics:
Nakano, Koji
Tatsumi, Go
Nozaki, Kyoko
The completely alternating copolymerization of propylene sulfide with carbon disulfide was first achieved. Copolymerization by using anionic initiator [Ph3P=N=PPh3]Cl gave poly(propylene trithiocarbonate). The addition of chromium complex was found to accelerate the copolymerization. The obtained copolymer has a completely alternating structure with high regioregularity and showed large refractive index of 1.781-1.782. Copyright
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