79413-15-3

Usage

Uses

Used in Adhesives and Coatings Industry:
2,2-Dimethyl-4-hexyl-1,3-dioxolane is used as a solvent for its ability to dissolve a wide range of substances, enhancing the performance and workability of adhesives and coatings.
Used in Cleaning Products Industry:
2,2-Dimethyl-4-hexyl-1,3-dioxolane is used as a solvent in cleaning products due to its effectiveness in dissolving dirt, grease, and other contaminants while maintaining low toxicity.
Used in Flavors and Fragrances Industry:
2,2-Dimethyl-4-hexyl-1,3-dioxolane is used as a solvent in the production of flavors and fragrances, allowing for the creation of stable and long-lasting scents.
Used in Pharmaceutical Synthesis:
2,2-Dimethyl-4-hexyl-1,3-dioxolane is used as an intermediate in the synthesis of pharmaceuticals, contributing to the development of new drugs and medications.
Used in Agricultural Chemicals Synthesis:
2,2-Dimethyl-4-hexyl-1,3-dioxolane is used as an intermediate in the synthesis of agricultural chemicals, aiding in the production of effective and stable agrochemicals.
It is important to handle 2,2-Dimethyl-4-hexyl-1,3-dioxolane with care, as prolonged exposure to high concentrations may cause irritation to the skin, eyes, and respiratory system.

Upstream product

• 111-66-0 oct-1-ene 
• 67-64-1 acetone 

Downstream Products

• 1117-86-8 1,2-octandiol 

Relevant academic research and scientific papers

Chromyl Complexes in the Direct Epoxidation of Alkenes

Alkenes such as (E)- and (Z)-β-methylstyrene are converted stereospecifically by dinitratodioxochromium(VI), or chromyl nitrate, to the corresponding epoxide with high selectivities in aprotic media under rather mild conditions.The presence of the cosolvents, N,N-dimethylformamide (DMF), acetone, pyridine, etc., is critical for effective epoxidation with this reagent.In DMF and pyridine, the epoxide remains generally intact but in acetone it is transformed to the corresponding alkene ketal which can also be isolated in high yields.The rates of oxidation are evaluated by the competition method, and the relative reactivities of various alkenes toward chromyl nitrate are found to generally parallel those previously determined for other chromyl reagents such as chromic acid, chromyl acetate, and chromyl chloride.Under optimum conditions for epoxidation, chromyl nitrate effects exclusive oxidation of 1,2-diphenylethanol to deoxybenzoin, which is uncontaminated by the usual cleavage products benzaldehyde and benzyl alcohol.Since the latter is known to derive from chromium(IV) intermediates, we conclude that the active species in chromyl epoxidation is oxochromium(V) formed in situ by the prior one-electron oxidation of solvent.The latter is in accord with the efficient transfer of the oxygen atom from macrocyclic oxochromium(V) species previously observed by Grovers and co-workers.The ESR spectra of the transient chromium(V) intermediates derived from chromyl nitrate and chromyl acetate by reduction with cosolvent are reported.