79413-84-6Relevant academic research and scientific papers
Amide-Directed C?H Sodiation by a Sodium Hydride/Iodide Composite
Huang, Yinhua,Chan, Guo Hao,Chiba, Shunsuke
, p. 6544 - 6547 (2017/05/29)
A new protocol for amide-directed ortho and lateral C?H sodiation is enabled by sodium hydride (NaH) in the presence of either sodium iodide (NaI) or lithium iodide (LiI). The transient organosodium intermediates could be transformed into functionalized aromatic compounds.
Lithiierung in α-Stellung zum N-Atom von Triphenylacetamiden aus cyclischen sekundaeren Aminen. Umlagerung metallierter Triphenylacetamide unter 1,3-Verschiebung der Carbamoylgruppe
Wykypiel, Werner,Lohmann, Jean-Jaques,Seebach, Dieter
, p. 1337 - 1346 (2007/10/02)
The reagents 2 - generally available by lithiation of the triphenylacetamides 1 - react with non-enolizable carbonyl compounds and benzyl halide (s.Tables 1 and 2, and products 3).The limits of thermal stability of metalated triphenylacetamides above 0 de
