79415-46-6Relevant academic research and scientific papers
Polybromoaromatic compounds: XI. Reactions of 2,3,4,5,6-pentabromobenzyl bromide with alcohols and alkali metal alkoxides
Shishkin,Vakaeva,Butin
, p. 709 - 712 (2007/10/03)
2,3,4,5,6-Pentabromobenzyl bromide reacts with primary and secondary alcohols and also with alkali metal alkoxides derived from primary alcohols to form the corresponding pentabromobenzyl ethers in high yields. In the reactions with secondary alkoxides, c
Polybromoaromatic compounds: IX. Reactions of polybromobenzyl bromides with enolates derived from some dicarbonyl compounds
Shishkin,Vakaeva,Belozerov,Tanaseichuk,Butin
, p. 975 - 980 (2007/10/03)
The reaction of polybromobenzyl bromides RC6Br4CH2Br (R = Br, OCH3) with diethyl malonate sodium salt in ethanol and dimethylformamide leads to formation of diethyl 2-(polybromobenzyl)malonates, whereas in aqueous ethanol ethyl polybromobenzyl malonates are formed. The same polybromobenzyl bromides react with an equimolar amount of ethyl acetoacetate sodium salt or acetylacetone sodium salt to give C-alkylation products; with excess sodium enolates ethyl 3-(polybromophenyl)propionates and 4-(polybromophenyl)-2-butanones are formed, respectively.
POLYBROMO AROMATIC COMPOUNDS. I. SYNTHESIS OF SOME DERIVATIVES CONTAINING A PENTABROMOPHENYL RESIDUE
Tanaseichuk, B. S.,Rumyantseva, K. S.,Vasin, V. A.,Shishkin, V. N.,Rumyantsev, N. P.,et al.
, p. 1124 - 1128 (2007/10/02)
The synthesis of pentabromobenzyl bromide has been carried out, and its nucleophilic substitution reactions with alcohols, amines, sodium acetate, and silver nitrite have been studied.The C-Br bond in the bromomethyl group of pentabromobenzyl bromide readily undergoes homolysis, resulting in reductive dehalogenation.
