79437-10-8Relevant academic research and scientific papers
Modulating the propeller-like shape of a tripodal C(CH2PPh2)3 fragment by the size of the substituent at the pivotal carbon atom in macrobicyclic tri-λ5-phosphazenes
Alajarín, Mateo,López-Leonardo, Carmen,Berná, José
, p. 4450 - 4458 (2008/02/03)
The chiral macrobicyclic tri-λ5-phosphazenes formed by tripod-tripod coupling of tris(3-azidobenzyl)amines and 1,1,1-tris[(diphenylphosphino)methyl]methanes present helical topologies as a result of combining two propeller-shaped tripodal fragm
PRODUCTION OF CYCLIC SULFITES AND THEIR TRANSFORMATION INTO SUBSTITUTED TRI(CHLOROMETHYL)METHANES
Bolotov, A. A.,Rodin, A. A.,V'yunov, K. A.,Ginak, A. I.,Sarkisov, Yu. S.
, p. 1812 - 1819 (2007/10/02)
The production of cyclic sulfites from trihydric alcohols and their conversion into chlorides by the action of DMFA-SOCl2 complex are described.By PMR and IR spectroscopy it was shown that cyclic sulfites exist preferentially in the chair conformation with the axial orientation of the S=O bond.It was established that the chlorides are formed in two parallel paths, i.e. directly from trihydric alcohols and their cyclic sulfites.
