13245-65-3Relevant academic research and scientific papers
Phenylselenium trichloride, preparation and use as a vinylic chlorination reagent
Stuhr-Hansen, Nicolai,Henriksen, Lars,Kodra, Janos T.
, p. 3345 - 3350 (1996)
Phenylselenium trichloride (1) is prepared from benzeneseleninic acid (2) and thionyl chloride and used to effect vinylic chlorination, viz. the conversion of 3-chloro-2-chloromethyl-1-propene (4) into 2-chloromethyl-1,3-dichloropropene (3).
Synthesis and Characterization of Polychlorinated Isobutenes
Schulze, K.,Hartmann, S.,Krueger, H.,Muehlstaedt, M.,Richter, C.,Richter, H.
, p. 433 - 442 (2007/10/02)
The preparation of polychlorinated methallylic chlorides by continuous chlorination of isobutene with different ratios of chlorine and following HCl-elimination is described.The structure is proved by reaction of the polychlorinated isobutenes with sodium thiolacetate and potassium thiocyanate and by spectroscopic methods.
