79491-36-4

Basic information

• Product Name: 3-<(4-methoxyphenyl)methylidene>-2-phenyl-4,5-dihydro-3H-pyrrole
• Synonyms: 3-<(4-methoxyphenyl)methylidene>-2-phenyl-4,5-dihydro-3H-pyrrole
• CAS NO: 79491-36-4
• Molecular Weight: 263.339
• Mol File: 79491-36-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-<(4-methoxyphenyl)methylidene>-2-phenyl-4,5-dihydro-3H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-<(4-methoxyphenyl)methylidene>-2-phenyl-4,5-dihydro-3H-pyrrole(79491-36-4)
• EPA Substance Registry System: 3-<(4-methoxyphenyl)methylidene>-2-phenyl-4,5-dihydro-3H-pyrrole(79491-36-4)

Safety Data

• Hazardous Substances Data: 79491-36-4(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 182324-83-0 4-methyl-N-(4-phenylbut-3-yn-1-yl)benzenesulfonamide 
• 100-66-3 methoxybenzene 
• 79491-30-8 N-<4-(4-metoxyphenyl)-4-oxobutyl>benzamide 
• 35340-63-7 3-benzoylaminobutanoic acid 
• 79491-33-1 N-<4-hydroxy-4-(4-methoxyphenyl)butyl>benzamide 

Relevant articles and documents

Domino Synthesis of 4-Alkylidene-3,4-dihydro-2H-pyrroles from Homopropargyl Sulfonamides and Aldehydes

Abstract: We describe a domino synthesis of 4-alkylidene-3,4-dihydro-2H-pyrroles from aryl-substituted homopropargyl sulfonamides and aldehydes promoted by cheap and easy-to-handle TsOH ? H2O. The present reactions proceed through cyclocondensation of α-sulfonamidoethyl-α,β-enone intermediates, which are formed by ring-cleavage of 3-acylpyrrolidines corresponding to aza-Prins cyclized intermediates. By controlling the conditions, 3-acylpyrrolidines can be obtained.

Bischler-Napieralski Reaction of N-(4-Aryl-4-hydroxybutyl)benzamides: Synthesis and X Ray Structure of (E)-3-Arylmethylidene-4,5-dihydro-3H-pyrroles

The N-(4-aryl-4-hydroxybutyl)benzamides (3a,b) have been cyclized under Bischler-Napieralski conditions to the 3-arylmethylidene-4,5-dihydro-3H-pyrroles (4a,b).These products are consistent with the formation of N-(4-arylbut-3-enyl)benzamide intermediates