795290-07-2

Upstream product

• 916221-17-5 4-O-(4-O-tert-butyldimethylsilyl-3-O-methyl-β-D-oleandropyranosyl)-3-O-triethylsilyl-L-olivomycal 
• 795290-06-1 (2R,3R,4S,5S,6R,1'R,2'S,4'S,2''R)-2-[1',2'-diacetoxy-5'-benzyloxy-4'-methoxy-pentyl]-4-triethylsilyloxy-6-[2''-hydroxy-3''-methoxypropyl]-2-methoxy-3,5-dimethyl-2,3,5,6-tetrahydro-4H-pyran 
• 795289-91-7 (3aR,6S,7S,7aR)-4-Methoxy-6-methyl-2-phenyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol 
• 795289-93-9 4,6-O-(di-tert-butyl)-silyliden-3-O-methyl-D-glucal 
• 795289-92-8 3-O-triethylsilyl-L-olivomycal 
• 916221-16-4 Toluene-4-sulfonic acid (2R,3S,4R)-3-hydroxy-4-methoxy-3,4-dihydro-2H-pyran-2-ylmethyl ester 
• 795289-94-0 4-O-tert-butyldimethylsilyl-3-O-methyl-6-O-tosyl-D-glucal 
• 847944-57-4 Toluene-4-sulfonic acid (2R,3R,4S,5R,6S)-3-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-4-methoxy-5-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester 
• 795289-95-1 O-(4-O-tert-butyldimethylsilyl-2-deoxy-3-O-methyl-2-thiophenyl-6-O-tosyl-α-D-glucopyranosyl)trichloroacetimidate 
• 795289-96-2 Toluene-4-sulfonic acid (2R,3R,4S,5R,6S)-3-(tert-butyl-dimethyl-silanyloxy)-6-((2S,3S,4S)-2,4-dimethyl-4-triethylsilanyloxy-3,4-dihydro-2H-pyran-3-yloxy)-4-methoxy-5-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester 
• 70717-92-9 4-O-acetyl-1,5-anhydro-1,2,6-trideoxy-3-C-methyl-L-arabino-hex-1-enitol 
• 13265-84-4 D-glucal 
• 191593-14-3 4,6-O-di(tert-butyl)silanediyl-D-glucal 
• 71072-42-9 3-O-Methyl-D-glucal 

Downstream Products

• 795290-08-3 C₆₁H₁₁₂O₁₇Si₃ 

Relevant academic research and scientific papers

Total synthesis of apoptolidin

A ring-size-selective macrolactonization and the early introduction of the saccharide portions are the main features of a total synthesis of the 20-membered macrolide apoptolidin (see formula), which induces apoptosis in rat glia cells transformed with oncogenes.