79563-59-0

Basic information

• Product Name: (-)-(1R,2R,5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexan-1-ol
• Synonyms: (-)-(1R,2R,5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexan-1-ol
• CAS NO: 79563-59-0
• Molecular Weight: 188.334
• Mol File: 79563-59-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (-)-(1R,2R,5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(1R,2R,5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexan-1-ol(79563-59-0)
• EPA Substance Registry System: (-)-(1R,2R,5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexan-1-ol(79563-59-0)

Safety Data

• Hazardous Substances Data: 79563-59-0(Hazardous Substances Data)

Upstream product

• 79563-63-6 (3aR,6R,7aR)-3,3,6-Trimethyl-hexahydro-benzo[d][1,2]oxathiole 2-oxide 
• 898541-20-3 5-methyl-2-<1-methyl-1-(benzylthio)ethyl>cyclohexanone 
• 79563-58-9 (2R,5R)-2-(1-Benzylsulfanyl-1-methyl-ethyl)-5-methyl-cyclohexanone 
• 120687-99-2 (S)-2-[2-(4-Chloro-phenyl)-ethyl]-2-hydroxy-3,3-dimethyl-butyraldehyde 
• 120687-96-9 (R)-2-[2-(4-Chloro-phenyl)-ethyl]-2-hydroxy-3,3-dimethyl-butyraldehyde 
• 407619-28-7 (2R,5R)-2-[1-(4-Heptyl-benzylsulfanyl)-1-methyl-ethyl]-5-methyl-cyclohexanone 
• 89-82-7 pulegone 
• 622840-40-8 8-mercaptomenthol 
• 266694-57-9 Phenyl-((2R,4aR,7R,8aR)-4,4,7-trimethyl-hexahydro-1-oxa-3-thia-naphthalen-2-yl)-methanone 
• 79618-03-4 (4aR,7R,8aR)-4,4,7-Trimethyl-hexahydro-1-oxa-3-thia-naphthalene 
• 79563-61-4 1-((2R,4aR,7R,8aR)-4,4,7-Trimethyl-hexahydro-1-oxa-3-thia-naphthalen-2-yl)-propan-1-one 
• 89556-32-1 2-((1'S)-1'-hydroxy-1'-phenylethyl)hexahydro-4,4,7-trimethyl-4H-1,3-benzoxathiin 
• 89556-33-2 2-<(1'S)-1'-hydroxy-1'-phenylpropyl>hexahydro-4,4,7-trimethyl-4H-1,3-benzoxathiin 
• 79563-62-5 (R)-3-((2R,4aR,7R,8aR)-4,4,7-Trimethyl-hexahydro-1-oxa-3-thia-naphthalen-2-yl)-hexan-3-ol 

Downstream Products

• 89556-33-2 2-<(1'S)-1'-hydroxy-1'-phenylpropyl>hexahydro-4,4,7-trimethyl-4H-1,3-benzoxathiin 
• 89556-32-1 2-((1'S)-1'-hydroxy-1'-phenylethyl)hexahydro-4,4,7-trimethyl-4H-1,3-benzoxathiin 
• 266694-57-9 Phenyl-((2R,4aR,7R,8aR)-4,4,7-trimethyl-hexahydro-1-oxa-3-thia-naphthalen-2-yl)-methanone 

Relevant articles and documents

Development of Odorless Thiols and Sulfides and Their Applications to Organic Synthesis

Development of new odorless thiols (dodecanethiol, 4-n- heptylphenylmethanethiol, 4-trimethylsilylphenylmethanethiol, 4-trimethylsilylbenzenethiol) and an odorless sulfide (1-methylsulfanyldodecane) and their applications to dealkylation, Michael addition, Swern oxidation, and Corey-Kim oxidation are described.

New reagent for the optical resolution of ketones: (-) (1R, 2R, 5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexanol. Application to trans dimethyl cyclopentanone-3,4-dicarboxylate

(-) (1R, 2R, 5R)-5-methyl-2-(1-mercapto-1-methylethyl)-cyclohexanol was shown to be a very powerful agent for the optical resolution of ketones. It was used for the resolution of trans dimethyl cyclopentanone-3,4-dicarboxylate combined with the epimerizat

ASYMMETRIC SYNTHESES BASED ON HEXAHYDRO-4,4,7-TRIMETHYL-1,3-BENZOXATHIANS

Earlier work concerned with a highly stereoselective asymmetric synthesis based on a 1,3-oxathiane as the chiral auxiliary reagent is reviewed and recent applications to the synthesis of the four stereoisomers of malyngolide, of (R)-(+)-γ-caprolactone (a