79629-42-8

Basic information

• Product Name: Benzene, [(2-bromo-2-propenyl)oxy]-
• CAS NO: 79629-42-8
• Molecular Formula: C9H9BrO
• Molecular Weight: 213.074
• Mol File: 79629-42-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-bromo-2-propenyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-bromo-2-propenyl)oxy]-(79629-42-8)
• EPA Substance Registry System: Benzene, [(2-bromo-2-propenyl)oxy]-(79629-42-8)

Safety Data

• Hazardous Substances Data: 79629-42-8(Hazardous Substances Data)

Upstream product

• 96-11-7 1,2,3-tribromopropane 
• 139-02-6 sodium phenoxide 
• 100-67-4 potassium phenolate 
• 513-31-5 2-bromoallyl bromide 
• 108-95-2 phenol 
• 1746-13-0 allyl phenyl ether 

Downstream Products

• 99029-95-5 2,3-bis(phenoxymethyl)buta-1,3-diene 
• 244056-20-0 1,1,2-tribromo-2-phenoxymethylcyclopropane 
• 13610-02-1 1-phenoxy-2-propyne 
• 36963-72-1 (3-phenoxyprop-1-en-2-yl)benzene 
• 1236063-70-9 (5,5-dimethyl-2-methylenehex-3-ynyloxy)benzene 
• 1236063-69-6 (2-methylenenon-3-ynyloxy)benzene 
• 133846-59-0 (E)-3-phenoxy-1-phenylsulphinylprop-1-ene 
• 133846-33-0 (Z)-3-phenoxy-1-phenylsulphinylprop-1-ene 
• 199923-53-0 1,2-diphenoxy-2-propene 
• 1746-13-0 allyl phenyl ether 
• 874194-31-7 2-(2-bromo-allyl)-phenol 
• 83338-55-0 2-Phenoxymethyl-2-phenyl-oxirane 
• 18229-83-9 (4,4-diethoxybut-2-ynyloxy)benzene 

Relevant articles and documents

Enantioselective Palladium(II)-Catalyzed Intramolecular Aminoarylation of Alkenes by Dual N?H and Aryl C?H Bond Cleavage

An asymmetric palladium-catalyzed intramolecular oxidative aminoarylation of alkenes has been developed with quinoline–oxazoline chiral ligands and Ag2CO3 as the oxidant. Various indolines containing a quaternary stereogenic center were synthesized in high yield with excellent enantioselectivity. Preliminary mechanistic studies suggest that the addition of a catalytic amount of phenylglyoxylic acid significantly accelerates the reaction and slightly enhances the enantioselectivity.

1,8-diazabicyclo[5.4.0]undec-7-ene-promoted regioselective elimination of vicinal dibromides having an adjacent O-and/or N-functional group

We have investigated the DBU-promoted HBr-elimination of vicinal dibromides having an adjacent O- and/or N-functional group under mild basic conditions. The elimination of 1-oxygenfunctionalized 2,3-dibromopropanes was more regioselective than that of 1-n

Synthesis of excitatory amino acid analogues

A general route to excitatory amino acid analogues has been developed as exemplified by the synthesis of A-1 and A-2. The key reactions involved were a Negishi coupling of Jackson's organozinc reagent with vinyl bromide 8 and subsequent ring closure of 15