36963-72-1

Upstream product

• 79629-42-8 2-bromoallyloxybenzene 
• 98-80-6 phenylboronic acid 
• 70-11-1 α-bromoacetophenone 
• 108-95-2 phenol 
• 721-04-0 2-phenoxy-1-phenylethanone 
• 81524-95-0 C₁₉H₁₈P 
• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 139-02-6 sodium phenoxide 
• 98-83-9 isopropenylbenzene 
• 100-67-4 potassium phenolate 

Downstream Products

• 143267-08-7 2,3-dihydro-2-methyl-2-phenylbenzofuran 
• 98-82-8 Isopropylbenzene 
• 13645-10-8 1-Phenoxy-2-phenyl-propan 
• 31378-03-7 1-phenyl-2-tosylethanone 
• 77130-15-5 2-phenylallyltrimethylsilane 
• 36963-74-3 2-Phenyl-1-buten-4-ol-(4,4-d⁽²⁾) 
• 36963-75-4 4-Brom-2-phenyl-1-buten-(4,4-d⁽²⁾) 
• 24066-86-2 (1-methylenehexyl)benzene 
• 104014-97-3 2-phenyl-3-(triethylsilyl)prop-1-ene 
• 98-83-9 isopropenylbenzene 
• 83338-55-0 2-Phenoxymethyl-2-phenyl-oxirane 
• 126583-99-1 1,2,3-trimethyl-3-(2-R-phenylallyl)-4-methylenecyclobutene 
• 5155-87-3 3-phenylbut-3-enoic acid 

Relevant academic research and scientific papers

Lewis-acid-mediated intramolecular trifluoromethylthiolation of alkenes with phenols: Access to SCF3-containing chromane and dihydrobenzofuran compounds

A Lewis-acid-mediated intramolecular trifluoromethylthiolation of alkenes with phenols that can offer direct access to SCF3-containing chromane and dihydrobenzofuran compounds was disclosed for the first time. Numerous SCF3-containing chromanes were obtai

The synthesis of ethanolamine libraries from olefin scaffolds

A solution-phase, multi-reaction sequence has been developed for the parallel synthesis of ethanolamine libraries. This approach uses 2,3-dibromopropene as a template for the synthesis of a small olefin sub-library, which is then further functionalized to

Reactivity of functionalized arylcarbenes. 2-Phenylethyl side chains and hetero analogues

Phenylcarbenes with -X-CH2Ph and -CH2-X-Ph (X = CH2, O, SiMe2) groups in the ortho position were generated thermally and photolytically from diazo or tosylhydrazone precursors. Stereorandom insertion reactions with β-C-H bonds were observed, pointing to a triplet abstraction-recombination mechanism. Large kinetic and stereochemical deuterium isotope effects support this notion. The ample formation of benzocyclobutenes from 2-CH2-X-Ph substrates is due to insertion of the carbenes into ArCH2-X bonds. Addition to the terminal phenyl groups competes with C-H and C-X insertion. The results of benzophenone sensitization and of trapping with methanol suggest that the intramolecular reactions of functionalized arylcarbenes proceed, at best, competitively with spin inversion.