79726-85-5

Basic information

• Product Name: methyl 2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranoside
• CAS NO: 79726-85-5
• Molecular Weight: 342.435
• Mol File: 79726-85-5.mol

Chemical Properties

• CAS DataBase Reference: methyl 2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranoside(79726-85-5)
• EPA Substance Registry System: methyl 2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranoside(79726-85-5)

Safety Data

• Hazardous Substances Data: 79726-85-5(Hazardous Substances Data)

Upstream product

• 3396-99-4 methyl α-D-galactopyranoside 
• 134262-93-4 (2S,3R,4S,5S,6R)-2-Methoxy-4-(4-methoxy-benzyloxy)-6-methyl-tetrahydro-pyran-3,5-diol 
• 100-39-0 benzyl bromide 
• 196807-67-7 Dithiocarbonic acid O-((2S,3R,4S,5S,6R)-3,5-bis-benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran-4-yl) ester S-methyl ester 
• 6109-60-0 methyl 3,6-dideoxy-α-D-xylo-hexopyranoside 

Downstream Products

• 79726-89-9 p-trifluoroacetamidophenyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside 
• 79726-93-5 9-[(2R,4aR,6S,7S,8S,8aR)-7-Acetoxy-8-((2R,3R,5R,6R)-3,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-nonanoic acid methyl ester 
• 79726-94-6 8-methoxycarbonyloct-1-yl 4,6-O-benzylidene-3-O-(2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside 
• 79726-90-2 p-trifluoroacetamidophenyl 3-O-(3,6-dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranoside 
• 247123-89-3 C₂₇H₃₂O₃SN₂ 
• 247123-88-2 C₂₆H₃₂O₆ 
• 247123-87-1 C₄₂H₅₀O₆Si 
• 247124-00-1 C₂₆H₃₂O₆ 
• 247123-98-4 C₂₆H₃₂O₅ 
• 247123-97-3 C₂₇H₃₆O₆ 
• 247124-06-7 C₂₇H₃₂O₄N₂ 
• 223664-31-1 Acetic acid (3R,5R,6R)-3,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester 
• 196807-41-7 Acetic acid (2R,3R,5R,6R)-3,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester 
• 196807-44-0 1,2-di-O-acetyl-4-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranose 

Relevant articles and documents

β-selective C-glycosidations: Lewis-acid mediated reactions of carbohydrates with silyl ketene acetals

Several examples of β-selective C-glycosidation reactions, involving TMSOTf-promoted addition of sterically hindered silyl ketene acetals to glucosyl and galactosyl acetates, are presented.

SYNTHESIS OF TWO 3-O-(3,6-DIDEOXY-α-D-xylo-HEXOPYRANOSYL)-α-D-MANNOPYRANOSIDES SUITABLE FOR COVALENT ATTACHMENT TO A PROTEIN CARRIER

3-O-(3,6-Dideoxy-α-D-xylo-hexopyranosyl)-α-D-mannopyranosides of 8-methoxycarbonyloctan-1-ol and of p-trifluoroacetamidophenol were synthesised by the reaction of 2,4-di-O-benzyl-3,6-dideoxy-α-D-xylo-hexopyranosyl bromide with suitable protected mannoside