79807-48-0Relevant articles and documents
Tin-free intermolecular addition of primary alkyls to imines via the dimethylzinc-air radical process
Yamada, Ken-Ichi,Yamamoto, Yasutomo,Maekawa, Masaru,Akindele, Tito,Umeki, Hiroyuki,Tomioka, Kiyoshi
, p. 87 - 89 (2006)
(Chemical Equation Presented) A dimethylzinc-air initiator was applied to the generation of primary alkyl radicals from alkyl iodides. The addition of the generated primary alkyl radicals to N-tosylimines was accelerated by the action of boron trifluoride
Iron-catalyzed N-alkylation using π-activated ethers as electrophiles
Fan, Xiaohui,Fu, Lin-An,Li, Na,Lv, Hao,Cui, Xiao-Meng,Qi, Yuan
, p. 2147 - 2153 (2013/04/10)
A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric Csp3-O cleavage with the C-N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated. The Royal Society of Chemistry 2013.