14674-38-5

Basic information

• Product Name: N-(4-METHOXY-BENZYLIDENE)-4-METHYL-BENZENESULFONAMIDE
• Synonyms: N-(4-METHOXY-BENZYLIDENE)-4-METHYL-BENZENESULFONAMIDE;N-(4-Methoxybenzylidene)-p-toluenesulfonamide;N-Tosyl(4-methoxyphenyl)methanimine;N-Tosyl-4-methoxybenzenemethanimine
• CAS NO: 14674-38-5
• Molecular Formula: C₁₅H₁₅NO₃S
• Molecular Weight: 289.35
• Mol File: 14674-38-5.mol
• Article Data: 118

Chemical Properties

• Melting Point: 127-132°C
• Appearance: /
• BRN: 2383265
• CAS DataBase Reference: N-(4-METHOXY-BENZYLIDENE)-4-METHYL-BENZENESULFONAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-METHOXY-BENZYLIDENE)-4-METHYL-BENZENESULFONAMIDE(14674-38-5)
• EPA Substance Registry System: N-(4-METHOXY-BENZYLIDENE)-4-METHYL-BENZENESULFONAMIDE(14674-38-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 14674-38-5(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 1058-14-6 N-p-tolylsulfonylphosphine imide 
• 70-55-3 toluene-4-sulfonamide 
• 622-58-2 p-Tolylisocyanate 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 58358-51-3 1-bromo-4-[2-(4-methoxyphenyl)vinyl]benzene 
• 1694-19-5 p-methoxystilbene 
• 4705-34-4 4,4'-dimethoxystilbene 
• 4083-64-1 Tosyl isocyanate 
• 105-13-5 4-Methoxybenzyl alcohol 
• 243671-18-3 N-[1-(4-methoxyphenyl)but-3-en-1-yl]-4-methylbenzenesulfonamide 
• 127-65-1 chloroamine-T 
• 54879-64-0 N-[(4-methoxyphenyl)methyl]-4-methylbenzenesulfonamide 
• 133039-38-0 tris(4-methylphenyl)bismuthane tosylimide 

Downstream Products

• 36315-64-7 diethyl [(E)-1-cyano-2-(4-methoxyphenyl)ethenyl]phosphonate 
• 370565-60-9 ethyl-2-diazo-3-(toluene-4-sulfonylamino)-3-(4-methoxyphenyl)-propanoate 
• 243671-18-3 N-[1-(4-methoxyphenyl)but-3-en-1-yl]-4-methylbenzenesulfonamide 
• 258277-16-6 N-tosyl-[(4-methoxyphenyl)(phenyl)methyl]amine 
• 212781-19-6 N-[2-Cyano-1-(4-methoxy-phenyl)-allyl]-4-methyl-benzenesulfonamide 

Relevant articles and documents

Copper-boryl mediated transfer hydrogenation of N-sulfonyl imines using methanol as the hydrogen donor

B2Pin2-assisted copper-catalyzed transfer hydrogenation of aromatic sulfonylimines has been achieved, delivering a variety of aryl/heteroaryl sulfonamides in good to excellent yields under mild reaction conditions and with methanol a

Mild Darzens Annulations for the Assembly of Trifluoromethylthiolated (SCF3) Aziridine and Cyclopropane Structures

We report mild new annulation approaches to trisubstituted trifluoromethylthiolated (SCF3) aziridines and cyclopropanes via Darzens inspired protocols. The products of these anionic annulations, rarely studied previously, possess attractive features rendering them valuable building blocks for synthesis platforms. In this study, trisubstituted acetophenone nucleophiles bearing SCF3 and bromine substituents in their α position were shown to undergo [2 + 1] annulations with vinyl ketones and tosyl-protected imines under mild reaction conditions.

Iron-based nanomaterials used as magnetic mesoporous nanocomposites to catalyze the preparation of N-sulfonylimines

A new magnetic nanocatalyzed synthetic method for the synthesis of aldimines was evidenced. The reaction was carried out in a Schlenk tube under reflux conditions using various solvents and different nanomaterials as catalysts. In these reactions, an exce