80006-90-2Relevant academic research and scientific papers
Regio- and Stereoselective Synthesis of (E)- and (Z)-Allylsulfones from Aldehydes and Alkynes
Ozawa, Motoyasu,Iwata, Noriyoshi,Kinoshita, Hideki,Inomata, Katsuhiko
, p. 1689 - 1692 (2007/10/02)
Several (E)- and (Z)-1-p-toluenesulfonyl(=tosyl)-2-alkenes, allylsulfones, were regio- and stereoselectively prepared from aldehydes and alkynes, respectively, in good yields by application of the results of our previous investigation on "syn-effect" and
REGIO- AND STEREOCONTROLLED SYNTHESIS OF ALLYLIC p-TOLYL SULFONES CATALYZED BY PALLADIUM (0) COMPLEX
Inomata, Katsuhiko,Yamamoto, Taku,Kotake, Hiroshi
, p. 1357 - 1360 (2007/10/02)
The reaction of allyl esters with sodium p-tolylsulfinate in tetrahydrofuran and methanol catalyzed by Pd(PPh3)4 gave the regio- and stereocontrolled allylic p-tolyl sulfones in good yields at room or lower temperature.
