35926-06-8

Usage

Physical state

Colorless liquid

Odor

Fruity

Uses

Production of perfumes, flavorings, and fragrance products; intermediate in the synthesis of organic compounds; flavoring agent in food products

Classification

Volatile organic compound

Safety precautions

Potential health hazards; follow manufacturer-provided handling and storage guidelines

InChI:InChI=1/C9H16O2/c1-4-6-7-9(5-2)11-8(3)10/h5,9H,2,4,6-7H2,1,3H3

Upstream product

• 68703-33-3 (E)-1-chloro-2-heptene 
• 127-09-3 sodium acetate 
• 110-62-3 pentanal 
• 4938-52-7 1-hepten-3-ol 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 592-76-7 1-Heptene 

Downstream Products

• 4938-52-7 (S)-Hept-1-en-3-ol 
• 4938-52-7 (3R)-1-hepten-3-ol 
• 3391-86-4 (S)-oct-1-en-3-ol 
• 3391-86-4 (R)-1-octene-3-ol 
• 22658-80-6 (R)-(+)-1-pentyl-2-propenyl acetate 
• 1182278-36-9 (E)-1-(4-methoxyphenyl)hept-1-en-3-yl acetate 
• 80006-90-2 1-[((E)-Hept-2-ene)-1-sulfonyl]-4-methyl-benzene 
• 72195-46-1 1-(hept-1-en-3-ylsulfonyl)-4-methylbenzene 
• 131156-32-6 1-[((Z)-Hept-2-ene)-1-sulfonyl]-4-methyl-benzene 

Relevant academic research and scientific papers

A Re2O7catalyzed cycloetherification of monoallylic diols

A Re2O7catalyzed cycloetherification of monoallylic diols is described. The reaction features short reaction time, mild reaction conditions and exclusive E selectivity. A wide range of monoallylic alcohols with alkyl or aryl substituents on olefin smoothly undergo ring closure to deliver corresponding oxa-heterocycles. The reaction is also operationally simple and not sensitive to air and moisture.

Atom transfer radical cyclization (ATRC) applied to a chemoenzymatic synthesis of Quercus lactones

The natural fragrances (+)-trans whisky lactone 2 and (+)-trans cognac lactone 4, together with a minor amount of their (-)-cis stereoisomers, were prepared in 50% and 42% overall yield, respectively, starting from racemic 1-hepten-3-ol (±)-5 and 1-octen-3-ol (±)-6. The procedure involved first the enantioconvergent, lipase mediated transformation of the secondary allylic alcohols derived dichloroacetates (±)-7 and (±)-8 into the corresponding homochiral (+)-7 and (+)-8, combined with their cyclization under a transition metal catalyzed atom transfer process.