80035-35-4

Upstream product

• 80035-34-3 2-((4aR,6R,7R,8R,8aS)-6,8-Bis-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-isoindole-1,3-dione 
• 156520-24-0 Benzyl 3-O-benzyl-2-desoxy-4,6-O-isopropylidene-2-phthalimido-β-D-glucopyranoside 
• 10022-13-6 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose 
• 80035-31-0 benzyl 2-phthalimido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside 
• 33868-53-0 tributylstannyl benzyl ether 
• 80035-33-2 benzyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 100-51-6 benzyl alcohol 
• 151266-88-5 Benzyl 2-desoxy-4,6-O-isopropylidene-2-phthalimido-β-D-glucopyranoside 
• 149342-15-4 benzyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 80035-32-1 benzyl 2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 191482-37-8 benzyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside 

Downstream Products

• 160137-77-9 2-[(2R,3R,4R,5S,6R)-2,4-Bis-benzyloxy-5-hydroxy-6-(4-methoxy-phenoxymethyl)-tetrahydro-pyran-3-yl]-isoindole-1,3-dione 
• 313658-53-6 benzyl 3-O-benzyl-2-deoxy-2-phthalimido-4,6-O-(2,3,4,6-tetra-O-benzyl-D-glucopyranosylidene)-β-D-glucopyranoside 
• 153805-00-6 benzyl 3-O-benzyl-2-deoxy-4-O-(3',6'-di-O-benzyl-2'-deoxy-2'-phthalimido-β-D-glucopyranosyl)-2-phthalimido-6-O-pivaloyl-β-D-glucopyranoside 
• 153804-99-0 benzyl 3-O-benzyl-2-deoxy-4-O-(3',6'-di-O-benzyl-4'-O-chloroacetyl-2'-deoxy-2'-phthalimido-β-D-glucopyranosyl)-2-phthalimido-6-O-pivaloyl-β-D-glucopyranoside 
• 1071226-19-1 (methyl 4,7,8,9-tetra-O-acetyl-3,5-dideoxy-5-trichloroacetamido-D-glycero-α-D-galacto-2-nonulopyranosylonate)-(2->6)-1,3-di-O-benzyl-2-deoxy-2-phthalimido-β-D-galactopyranoside 
• 1401439-77-7 (methyl 4,7,8,9-tetra-O-acetyl-3,5-dideoxy-5-trichloroacetamido-D-glycero-β-D-galacto-2-nonulopyranosylonate)-(2->6)-1,3-di-O-benzyl-2-deoxy-2-phthalimido-β-D-galactopyranoside 
• 80035-37-6 benzyl O-[2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl]-(1-4)-3,6-di-O-benzyl-2-deoxy-2-N-phthalimido-β-D-glucopyranoside 
• 156520-27-3 Benzyl 2-allyloxycarbonylamino-3,6-di-O-benzyl-2-desoxy-β-D-glucopyranoside 
• 330999-05-8 Benzyl 3,6-di-O-benzyl-2-deoxy-2-amino-β-D-glucopyranoside 
• 207917-29-1 benzyl 6-O-[4-O-acetyl-3-O-(4-methoxybenzyl)-2-O-methyl-α-L-fucopyranosyl]-4-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-3-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 207917-30-4 C₆₆H₇₆N₄O₁₆ 
• 207917-28-0 benzyl 4-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-3-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 163069-87-2 acetic acid 4-benzyloxy-2-benzyloxymethyl-6-[4,6-bis-benzyloxy-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-2-(4-methoxy-phenoxymethyl)-tetrahydro-pyran-3-yloxy]-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-tetrahydro-pyran-3-yl ester 
• 163069-88-3 C₆₃H₅₈N₂O₁₄ 

Relevant academic research and scientific papers

Synthesis of an α-(2,3)-sialylated, complex-type undecasaccharide

Only two building blocks were necessary to provide efficient access to the complex undecasaccharide 1 by means of two stereo- and regioselective glycosylation reactions. Stereocontrolled p-methoxybenzyl-assisted β- mannosylation afforded the critical β-ma

TCP- and phthalimide-protected n-pentenyl glucosaminide precursors for the synthesis of nodulation factors as illustrated by the total synthesis of nodRf-III (C18:1, MeFuc)

TCP- and phthalimide-protected n-pentenyl glucosaminide (NPG) precursors have been utilized in a convergent stereocontrolled synthesis of the nodulation factor NodRf-III (C18:1, MeFuc) produced by Rhizobium fredii USDA257, 2. Nodulation factors are lipool

RECTIVITE COMPAREE DE DIVERS ACCEPTEURS DE LA D-GLUCOSAMINE LORS DE LA SYNTHESE DE PRECURSEURS DU CHITOBIOSE

Six D-glucosamine derivatives, diversely substituted at the nitrogen atom, were tested as acceptors in glycosylation reactions with 1,3,4,6-tetra-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranose (1) as the donor and trimethylsilyl trifluoromethanesulfonate as the promoter.The observed yields were high with 2-phthalimido- and 2-azido-D-glucosamine acceptors and more generally good with acceptors of the 1,6-anhydro-D-glucosamine series.The disaccharides benzyl 4-O-(3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranosyl)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside (20), benzyl 4-O-(3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranosyl)-2-allyloxycarbonylamino-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside (21), 4-O-(3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranosyl)-1,6-anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose (22), 4-O-(3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranosyl)-2-allyloxycarbonylamino-1,6-anhydro-3-O-benzyl-2-deoxy-β-D-glucopyranose (23), 2-acetamido-4-O-(3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranosyl)-1,6-anhydro-3-O-benzyl-2-deoxy-β-D-glucopyranose (24) and 2-acetamido-4-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-1,6-anhydro-3-O-benzyl-2-deoxy-β-D-glucopyranose (25) have thus been synthesized.

Chemical Synthesis of Nod-Rm-1: the Nodilation Factor Involved in Rhizobium meliloti-legume Symbiosis

A total synthesis of the sulfated lipotetrasaccharide (NodRm-1) is described.First, the disaccharide glycosyl donor - O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl chloride 3a or

SYNTHESIS OF 3,6-DI-O-ACETYL-2-DEOXY-2-PHTHALIMIDO-4-O-(2,3,4,6-TETRA-O-ACETYL-β-D-GALACTOPYRANOSYL)-β-D-GLUCOPYRANOSYL CHLORIDE

A lactosaminyl donor, 3,6-di-O-acetyl-2-deoxy-2-phthalimido-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-glucopyranosyl chloride, was synthesized in 10 steps, starting from 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose.Benzyl 3,6