80035-37-6

Upstream product

• 80035-36-5 benzyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-beta-D-glucopyranoside 
• 3068-32-4 1-bromo-1-deoxy-2,3,4,6-tetra-O-acetyl-a-D-galactopyranoside 
• 80035-31-0 benzyl 2-phthalimido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside 
• 10022-13-6 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose 
• 4163-60-4 β-D-galactose peracetate 
• 80035-32-1 benzyl 2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 33868-53-0 tributylstannyl benzyl ether 
• 80035-34-3 2-((4aR,6R,7R,8R,8aS)-6,8-Bis-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-isoindole-1,3-dione 
• 80035-33-2 benzyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 80035-35-4 benzyl 3-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 

Downstream Products

• 799830-34-5 trifluoro-methanesulfonic acid 4-allyloxycarbonyloxy-6-allyloxycarbonyloxymethyl-2-[4,6-bis-benzyloxy-2-benzyloxymethyl-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-tetrahydro-pyran-3-yloxy]-5-trifluoromethanesulfonyloxy-tetrahydro-pyran-3-yl ester 
• 799830-36-7 Acetic acid (2S,3S,4S,5R,6R)-5-acetoxy-4-allyloxycarbonyloxy-6-allyloxycarbonyloxymethyl-2-[(2R,3S,4R,5R,6R)-4,6-bis-benzyloxy-2-benzyloxymethyl-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

SYNTHESIS OF 3,6-DI-O-ACETYL-2-DEOXY-2-PHTHALIMIDO-4-O-(2,3,4,6-TETRA-O-ACETYL-β-D-GALACTOPYRANOSYL)-β-D-GLUCOPYRANOSYL CHLORIDE

A lactosaminyl donor, 3,6-di-O-acetyl-2-deoxy-2-phthalimido-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-glucopyranosyl chloride, was synthesized in 10 steps, starting from 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose.Benzyl 3,6

An improved method for synthesizing antennary β-D-mannopyranosyl disaccharide units

The merits of an indirect protecting method for hydroxyl groups using allyl groups via allyloxycarbonyl groups in the synthesis of antennary β-D-mannopyranosyl disaccharides from β-D-galactopyranosyl disaccharides were studied. Regioselective allyloxycarbonylation and conversion reactions involving simultaneous double SN2 nucleophilic substitution at C-2′ and C-4′ of benzyl O-[β-D-galactopyranosyl]-(1-4)-3,6- di-O-benzyl-2-deoxy-2-N-phthalimido-β-D-glucopyranoside were examined for comparison with the direct allylation method. The required β-D- mannopyranosyl disaccharide having proper protecting groups was obtained using this indirect method in 52% yield. In contrast, the reported direct allylation method using methyl O-(β-D-galactopyranosyl) disaccharide gave the corresponding β-D-mannopyranosyl disaccharide in only 7.5% yield.