80056-40-2Relevant academic research and scientific papers
Moderate generation of sulfenylnitrenes from novel N-sulfenylsulfodiimides
Yoshimura, Toshiaki,Fujie, Tetsuo,Fujii, Takayoshi
, p. 427 - 430 (2008/02/04)
N-Sulfenylated sulfodiimides were first prepared by the reaction of S,S-diphenyl-N-tosylsulfodiimide with arenesulfenyl chlorides under the basic conditions. Thermolysis of S,S-diphenyl-N-(2-nitrophenylsulfenyl)- and S,S-diphenyl-N-(2,4-dinitrophenylsulfe
An Efficient Thermal Route to Arenesulphenylnitrenes
Atkinson, Robert S.,Lee, Michael,Malpass, John R.
, p. 919 - 920 (2007/10/02)
Arenesulphenylnitrenes are generated efficiently from sulphenamides, (1), on heating at ca. 80 - 120 deg C and are trapped by alkenes as the corresponding aziridines in quantitative yield; this approach is shown to be more efficient and more widely applic
2,4-Dinitrobenzenesulphenylnitrene: Addition to (Z)- and (E)-1-Phenylpropene
Atkinson, Robert S.,Judkins, Brian D.,Khan, Naeema
, p. 2491 - 2498 (2007/10/02)
Oxidation of 2,4-dinitrobenzenesulphenamide (1) with lead tetra-acetate in the presence of (Z)-1-phenylpropene gives a ca. 3:1 mixture of cis- and trans-aziridines (3) and (4), respectively.This ratio is unchanged over a ten-fold decrease in concentration
Intermolecular Trapping of Sulphenylnitrenes by Alkenes
Atkinson, Robert S.,Judkins, Brian D.
, p. 2615 - 2619 (2007/10/02)
Oxidation of 2,4-dinitrobenzenesulphenamide with lead tetra-acetate in the presence of electron-rich alkenes (styrene, (E)- and (Z)-1-phenylpropene, 2-phenylpropene, (Z)-but-2-ene, and butadiene) gives the corresponding substituted N-(2,4-dinitrophenylsulphenyl))aziridines.Intermolecular trapping of a presumed sulphenylnitrene intermediate is also successful in the oxidation of 2-nitrobenzenesulphenamide but fails for RSNH2 when R = PhCO, 4-ClC6H4, or 4-NO2C6H4.
