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80077-72-1

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80077-72-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 80077-72-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,0,7 and 7 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 80077-72:
(7*8)+(6*0)+(5*0)+(4*7)+(3*7)+(2*7)+(1*2)=121
121 % 10 = 1
So 80077-72-1 is a valid CAS Registry Number.

80077-72-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name [diethoxyphosphoryl(difluoro)methyl]-trimethylsilane

1.2 Other means of identification

Product number -
Other names DIETHYL [DIFLUORO(TRIMETHYLSILYL)METHYL]PHOSPHONATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:80077-72-1 SDS

80077-72-1Relevant articles and documents

Electrochemical synthesis of fluoro-organosilanes

Martynov,Stepanov

, p. 127 - 128 (1997)

The electrochemical reduction of some fluorohalocarbons in the presence of trimethylchlorosilane is followed by formation of the corresponding fluoroalkyltrimethylsilanes. CF3SiMe3, CFCl2SiMe3, CF3CCl2SiMe3 and (EtO)2P(O)CF2SiMe3 were obtained with current efficiency 20-50%. Voltammetric data are presented.

Siladifluoromethylation and Deoxo-trifluoromethylation of PV-H Compounds with TMSCF3: Route to PV-CF2- Transfer Reagents and P-CF3 Compounds

Krishnamurti, Vinayak,Barrett, Colby,Prakash, G. K. Surya

, p. 1526 - 1529 (2019/03/07)

A method for siladifluoromethylation of dialkyl phosphonates and secondary phosphine oxides with TMSCF3 to produce nucleophilic PV-CF2- transfer reagents is disclosed, with multigram scale reactions included. Condition-dependent divergent reactivity under the established conditions is demonstrated by the formation of trifluoromethylphosphines. Both one-pot transformations are operationally simple and employ inexpensive materials. Mechanistic investigations suggest the divergent reactivity originates from a common intermediate, with Li+ concentration directing the chemoselectivity.

Reactions of sulfur- and phosphorus-substituted fluoroalkylating silicon reagents with imines and enamines under acidic conditions

Kosobokov, Mikhail D.,Dilman, Alexander D.,Struchkova, Marina I.,Belyakov, Pavel A.,Hu, Jinbo

supporting information; experimental part, p. 2080 - 2086 (2012/04/23)

Nucleophilic fluoroalkylation reactions of imines and enamines with α-phenylthio, α-phenylsulfonyl, and α-diethylphosphoryl substituted fluorinated silanes have been investigated. The reactions are promoted by hydrofluoric acid generated in situ from pota

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