80102-38-1

Basic information

• Product Name: 5-imino-3,4,4-trimethyl-thiazolidine-2-thione; compound with 5,5-dimethyl-imidazolidine-2,4-dithione
• CAS NO: 80102-38-1
• Molecular Weight: 508.846
• Mol File: 80102-38-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-imino-3,4,4-trimethyl-thiazolidine-2-thione; compound with 5,5-dimethyl-imidazolidine-2,4-dithione(CAS DataBase Reference)
• NIST Chemistry Reference: 5-imino-3,4,4-trimethyl-thiazolidine-2-thione; compound with 5,5-dimethyl-imidazolidine-2,4-dithione(80102-38-1)
• EPA Substance Registry System: 5-imino-3,4,4-trimethyl-thiazolidine-2-thione; compound with 5,5-dimethyl-imidazolidine-2,4-dithione(80102-38-1)

Safety Data

• Hazardous Substances Data: 80102-38-1(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 2273-39-4 2-methylamino-2-methylpropanenitrile 

Downstream Products

• 20513-25-1 5,5-dimethylimidazolidine-2,4-dithione 
• 80102-31-4 imino-5 trimethyl-3,4,4 thiazolidine thione-2 

Relevant articles and documents

The reaction between carbon disulfide and some α-methylaminonitriles. The supposed isomerism of 4,4-dialkyl-5-imino-3-methylthiazolidine-2-thiones

The reaction of carbon disulfide with α-methylaminonitriles 1 yields 5-iminothiazolidine-2-thiones 3, which on prolonged reaction are converted to 5-methyliminothiazolidine-2-thiones 5 and 2,4-dithiohydantoins 9.A mechanism for this apparent methyl transfer is advanced.The yellow compounds obtained by prolonged reaction of the aminonitriles 1 (R1 = R2 = Me and R1 = Et, R2 = Me) are not isomers of the imines 3 (R1 = R2 = Me and R1 = Et, R2 = Me), but 2:1 complexes of these imines with the corresponding 2,4-dithiohydantoins 9 (R1 = R2 = Me and R1 = Et, R2 = Me).