80135-19-9Relevant articles and documents
Synthesis method of bi(2-aminoisobutyl)amine
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Paragraph 0021, (2018/07/07)
The invention relates to a synthesis method of bi(2-aminoisobutyl)amine. According to the method provided by the invention, 2-aminoisobutanol and an ammoniation agent are used as raw materials and arecatalytically synthesized into the bi(2-aminoisobutyl)amine under a hydrogen gas condition; the method comprises the following steps: (1) adding the 2-aminoisobutanol, the ammoniation agent and a catalyst into a high-pressure kettle; (2) introducing a certain amount of hydrogen gas and reacting for 6h to 15h under the condition that the temperature is 160 DEG C to 200 DEG C; (3) after reaction isfinished, filtering to remove the catalyst and rectifying a reaction solution to obtain a pure product of the bi(2-aminoisobutyl)amine. With the adoption of the method, a synthesis process is clean and simple to operate; a target product can be obtained through one-step reaction and the synthesis method is applicable to large-scale preparation.
Piperazinone derivatives
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, (2008/06/13)
A compound of the formula (I) wherein n is preferably 3; G1, G2, G3 and G4 are independently of one another e.g. C1-C4alkyl; A1 is e.g. hydrogen or methyl; A2 is e.g. methylene; A3′ and A3″ are e.g. C1-C4alkyl; A4 is e.g. C1-C8alkyl; Y is e.g. a group of the formula (IV) wherein R1 is e.g. hydrogen or methyl, R2 is e.g. methylene, R3′ and R3″ are e.g. C1-C4alkyl and R4 is e.g. hydrogen or C1-C8alkyl; and Z is e.g. a group of the formula (VI) with A10′ and A10″ being independently of one another e.g. hydrogen or C1-C4alkyl and A11′ and A11″ being independently of one another e.g. C2-C6alkylene, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.