80185-60-0Relevant academic research and scientific papers
Reaction of (+)carvomenthol tosylate with KCN in aprotic solvents; (1S,2R,4S) 1-methyl-4-isopropylcyclohexane-2-carbonitrile
Rykowski, Zbigniew
, p. 2271 - 2278 (2007/10/02)
Reaction of (+)carvomenthol tosylate with KCN in pyridine solution was proved to produce a mixture of hydrocarbons; in DMF additionally a small quantity of alcohols was obtained.However, in DMSO sterically homogeneous (-)(1S,2R,4S) 1-methyl-4-isopropylcyclohexane-2-carbonitrile ((-)neocarvomenthyl carbonitrile) was the main product.The structure of the compound obtained was determined on the basis of spectral data, elemental analysis, and chemical transformations which indicated configurational relation of the title compound to the known (-)(1S,2R,4S) neocarvomenthyl amine.
REACTIONS OF UNSATURATED TERPENE COMPOUNDS WITH CHLORAMINE-T. PART I. (1R,2S,4S)-1-HYDROXY-2-(p-TOLUENESULFONAMIDO)-p-MENTHANE AND (1S,2S,3R)-2-HYDROXY-3-(p-TOLUENESULFONAMIDO)-PINANE
Rykowski, Zbigniew,Wrzesien, Justyna
, p. 371 - 377 (2007/10/02)
Reactions of p-menth-1-ene and α-pinene with chloramine-T in presence of catalytic quantities of OsO4 have been investigated.Homogeneous products were isolated, the structure of which was established on the basis of spectral analyses and chemical transfor
