80235-68-3Relevant academic research and scientific papers
Phosphatidyl myo-inositol mannosides mimics built on an acyclic or heterocyclic core: Synthesis and anti-inflammatory properties
Front, Sophie,Court, Nathalie,Bourigault, Marie-Laure,Rose, Stephanie,Ryffel, Bernhard,Erard, Francois,Quesniaux, Valerie F.J.,Martin, Olivier R.
scheme or table, p. 2081 - 2093 (2012/07/01)
Phosphatidyl myo-inositol mannosides (PIMs) are constituents of the mycobacterial cell wall and possess immunomodulatory activities. Certain PIM derivatives have immunoprotective activity and are of interest as anti-inflammatory agents. In order to identi
Stereocontrolled elaboration of natural (-)-polycavernoside A, a powerfully toxic metabolite of the red alga Polycavernosa tsudai
Paquette, Leo A.,Barriault, Louis,Pissarnitski, Dmitri,Johnston, Jeffrey N.
, p. 619 - 631 (2007/10/03)
A stereoselective total synthesis of natural levorotatory polycavernoside A (1) has been achieved. Initial investigations produced the properly activated disaccharide unit 18b via the conjoining of building blocks originating from L-fucose and D-xylose. T
STUDIES DIRECTED TOWARD THE TOTAL SYNTHESIS OF POLYCAVERNOSIDE A. ENANTIOSELECTIVE SYNTHESIS OF THE DISACCHARIDE COMPONENT
Johnston, Jeffrey N.,Paquette, Leo A.
, p. 4341 - 4344 (2007/10/02)
Adaptation of the Mukaiyama-Nicolaou protocol to the coupling of a monounprotected thioglycoside to a glycosyl fluoride is capable of delivering the unusual disaccharide present in the title toxin.
