80312-55-6

Upstream product

• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 2083-91-2 N,N-Dimethyltrimethylsilylamine 
• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 
• 75-77-4 chloro-trimethyl-silane 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 80312-59-0 methoxymethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109153-77-7 (1'S)-1-methoxybutyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109181-75-1 (1'R)-1-methoxybutyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109153-82-4 (1')-2-chloro-1-methoxyethyl 2,3,4,6-tetra-O-benzyl-β-D-glucoyranoside 
• 109153-83-5 (1'S)-2-chloro-1-methoxyethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 30608-21-0 1-O-trimethylsilyl-2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 109153-81-3 (1'S)-1,2-dimethoxyethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109153-80-2 (1'R)-1,2-dimethoxyethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109153-76-6 (1'S)-1-methoxy-2-phenylethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109153-75-5 (1'R)-1-methoxy-2-phenylethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 74080-40-3 (2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside 
• 25018-28-4 2,3,4,6-tetrabenzyl-α-D-mannopyranosyl-(1->1)-2,3,4,6-tetrabenzyl-α-D-mannopyranoside 
• 951764-84-4 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-gluco-hept-ulopyranosyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 109153-84-6 (1'R)-2-bromo-1-ethoxyethyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Stereoselective trimethylsilylation of α- and β-galactopyranoses

Trimethylsilylation of the anomeric hydroxyl groups of tetra-O-benzyl and tetra-O-acetyl galactopyranoses was investigated. Stereoselective formation of β-trimethylsilyl glycoside (β-TMS glycoside) of benzyl protected compound was achieved using N-trimeth

Palladium-catalyzed silylation of alcohols with hexamethyldisilane

The combination of hexamethyldisilane and a catalytic amount of [PdCl(η3-C3H5)]2-PPh 3 was found to be effective for the trimethylsilylation of alcohols, where both of the two trimethylsilyl groups of hexamethyldisilane were transferred to alcohols without coproduction of any stoichiometric amount of byproduct but H2. The Royal Society of Chemistry 2006.