80318-41-8Relevant academic research and scientific papers
Reactions Involving Fluoride Ion. Part 40. Amines as Initiators of Fluoride Ion Catalysed Reactions
Chambers, Richard D.,Gray, William K.,Korn, Stewart R.
, p. 13167 - 13176 (2007/10/03)
Tetrakis(dimethylamino)ethene (TDAE) and trimethylamine react with anhydrous unsaturated fluorocarbons to produce, 'in situ', powerful fluoride-ion sources.These are used to iniate carbon-carbon bond forming reactions eg. oligomerisation and polyfluoroalkylation, and many of these reactions occur efficiently in the absence of a solvent.
Hexacoordinated Sulfur(VI) and Ψ-Hexacoordinated Sulfur(IV) Anions
Heilemann, Werner,Mews, Ruediger,Pohl, Siegfried,Saak, Wolfgang
, p. 427 - 432 (2007/10/02)
(Me2N)3S+OSF5- (3) was prepared from OSF4 and (Me2N)3S+Me3SiF2- ("TAS fluoride ", 1).From 1 and SF4, CF3SF3, and (CF2)2CFSF3, TAS+SF5- (5a), TAS+CF3SF4- (5b), and TAS+(CF3)2CFSF4- (5c) were obtained.Spectroscopic data of these salts and the crystal structure of 3 are reported. - Keywords: Pentafluorooxosulfate ion/ Sulfur anions, fluorine-containing/ Sulfur tetrafluoride derivatives/ Tris(dimethylamino)sulfonium difluorotrimethylsilicate
Fluorinated Tertiary Thio- and Selenoethers from the Reaction of Sulfenyl or Selenenyl Chloride with Perfluoropropene Dimers in the Presence of Alkali Fluoride
Suzuki, Hitomi,Satake, Hiroshi,Uno, Hidemitsu,Shimizu, Hiroaki
, p. 4471 - 4473 (2007/10/02)
Perfluoro(1,1-dimethylbutanide) anion generated from hexafluoropropene dimers and alkali fluorides in dry N,N-dimethylformamide, reacts with arenesulfenyl or areneselenenyl chloride to give the corresponding aryl perfluoro(1,1-dimethylbutyl) sulfides or selenides in low to good yields.
