80351-84-4

Basic information

• Product Name: N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide
• Synonyms: N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide
• CAS NO: 80351-84-4
• Molecular Weight: 458.024
• Mol File: 80351-84-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide(80351-84-4)
• EPA Substance Registry System: N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide(80351-84-4)

Safety Data

• Hazardous Substances Data: 80351-84-4(Hazardous Substances Data)

Upstream product

• 77855-66-4 N-(α-chlorobenzyl)-N-benzyl-p-chlorobenzamide 
• 100-53-8 phenylmethanethiol 
• 780-25-6 N-benzylidene benzylamine 
• 80351-83-3 N-Benzyl-N-[(4-chloro-benzylsulfanyl)-phenyl-methyl]-benzamide 
• 80351-85-5 N-Benzyl-N-[(4-methyl-benzylsulfanyl)-phenyl-methyl]-benzamide 
• 80351-82-2 N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-benzamide 
• 122-01-0 4-chloro-benzoyl chloride 

Downstream Products

• 451-40-1 phenyl benzyl ketone 
• 80351-87-7 N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-propionamide 
• 80351-86-6 N-Benzyl-N-(phenyl-propylsulfanyl-methyl)-benzamide 
• 80351-82-2 N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-benzamide 
• 80351-83-3 N-Benzyl-N-[(4-chloro-benzylsulfanyl)-phenyl-methyl]-benzamide 
• 780-25-6 N-benzylidene benzylamine 
• 1889-71-0 4'-chloro-2-phenylacetophenone 

Relevant articles and documents

NOVEL REARRANGEMENTS OF α-N-ALKYLAMIDO-SUBSTITUTED SULFIDES AND SULFONES

The present paper describes novel rearrangements of α-N-alkylamido-substituted sulfides and sulfones promoted by strong bases such as NaH, lithium diisopropylamide and butyllithium, where the alkyl group linked to the sulfur migrates to the amide carbonyl carbon to give the corresponding ketones.The reactions are established as intramolecular rearrangements, and the mechanism is discussed.Keywords: - alkyl (N-alkylamido)methyl sulfide; alkyl (N-alkylamido)methyl sulfone; alkyl α-(N-alkylamido)benzyl sulfide; intramolecular rearrangement; sodium hydride; lithium diisopropylamide; butyllithium