80356-58-7

Upstream product

• 939-16-2 3-bromoquinolin-2-one 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 120568-93-6 1-iodo-2-[(3-phenylprop-2-enyl)oxy]benzene 
• 552-89-6 2-nitro-benzaldehyde 
• 13939-06-5 molybdenum hexacarbonyl 
• 53244-92-1 (2-oxo-1,2-dihydro-quinolin-3-yl)-acetic acid 
• 100-52-7 benzaldehyde 
• 80356-52-1 3-[1-Phenyl-meth-(Z)-ylidene]-3H-furo[2,3-b]quinolin-2-one 
• 80356-55-4 α-(2-quinolon-3-yl)-cinnamic acid 

Downstream Products

• 80356-74-7 3-(2'-phenylethyl)-quinolin-2-(1H)-one 
• 1309690-17-2 (3-phenyloxiran-2-yl)quinolin-2(1H)-one 
• 1309690-18-3 1-methyl-(3-phenyloxiran-2-yl)quinolin-2(1H)-one 
• 80356-75-8 (E)-1-methyl-3-styrylquinolin-2-one 

Relevant academic research and scientific papers

Palladium-Catalyzed Reductive Aminocarbonylation of o-Iodophenol-Derived Allyl Ethers with o-Nitrobenzaldehydes to 3-Alkenylquinolin-2(1 H)-ones

An attractive palladium-catalyzed reductive aminocarbonylation reaction of allylic ethers has been explored for the synthesis of 3-alkenylquinolin-2(1H)-one derivatives. With Mo(CO)6as both CO surrogate and reductant, a variety of 3-alkenylquinolin-2(1H)-ones were obtained in good to excellent yields from o-iodophenol-derived allyl ethers with o-nitrobenzaldehydes as the nitrogen sources. This reaction proceeds through a cascade pathway and does not rely on high-pressure CO gas as needed in former allylic carbonylation reactions. This strategy provides a new pathway for the construction of 3-alkenylquinolin-2(1H)-ones.

Synthesis of catalytically active ruthenium complexes with a remote chiral lactam as hydrogen-bonding motif

A terminal alkyne was prepared, which is linked by a carbon-carbon bond to a conformationally restricted, U-shaped chiral lactam, that is, more precisely, to carbon atom C7 of 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one. The alkyne was connected to var