80373-62-2

Upstream product

• 17904-27-7 (+)-(4R)-[(S)-1,5-dimethyl-3-oxohexyl]cyclohex-1-enecarboxylic acid methyl ester 
• 80373-72-4 (R)-5-[(1S,3R)-3-(tert-Butyl-diphenyl-silanyloxy)-1,5-dimethyl-hexyl]-2-methyl-cyclohexanone 
• 80373-75-7 [(1R,3S)-3-((R)-4-Bromomethyl-cyclohex-3-enyl)-1-isobutyl-butoxy]-tert-butyl-diphenyl-silane 
• 80373-78-0 (R)-4-[(1S,3R)-3-(tert-Butyl-diphenyl-silanyloxy)-1,5-dimethyl-hexyl]-cyclohex-1-enecarbaldehyde 
• 80373-81-5 (R)-4-[(1S,3R)-3-(tert-Butyl-diphenyl-silanyloxy)-1,5-dimethyl-hexyl]-cyclohex-1-enecarboxylic acid methyl ester 
• 26575-87-1 (+)-epijuvabione 
• 186581-53-3 diazomethane 
• 145353-91-9 methyl (1S,4S,1'S)-(-)-4-(1'-methyl-2'-propenyl)-2-cyclohexenecarboxylate 
• 145414-44-4 methyl (4R,1'S)-(+)-4-(1'-methyl-2'-propenyl)-1-cyclohexencarboxylate 
• 145353-90-8 (1S,4S,1'S)-(-)-4-(1'-methyl-2'-propenyl)-2-cyclohexenylmethanol 
• 145414-43-3 (3aS,7aR)-(+)-2,3,3a,4,5,7a-hexahydrobenzofuran-2-one 
• 145353-87-3 (3S,3aS,7aR)-(+)-methyl-2,3,3a,4,5,7a-hexahydrobenzfuran-2-one 
• 145353-89-5 (1S,6S,1'S)-(+)-2-(1'-methyl-2'-propenyl)-5-cyclohexen-1-ol 
• 68069-67-0 (1S,4S)-(-)-bicyclo<2.2.2>oct-5-en-2-one 

Downstream Products

• 38963-91-6 4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohexanecarboxylic acid 
• 38963-91-6 4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohexanecarboxylic acid 
• 86279-09-6 cis-4-<3(S)-hydroxy-1(R),5-dimethylhexyl>cyclohexane-1-carboxylic acid 
• 86279-09-6 trans-4-<3(S)-hydroxy-1(R),5-dimethylhexyl>cyclohexane-1-carboxylic acid 
• 38963-60-9 4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohexanecarboxylic acid methyl ester 
• 17844-06-3 (R)-4-((R)-3-Hydroxy-1,5-dimethyl-hexyl)-cyclohex-1-enecarboxylic acid 
• 17904-27-7 (+)-(4R)-[(S)-1,5-dimethyl-3-oxohexyl]cyclohex-1-enecarboxylic acid methyl ester 

Relevant academic research and scientific papers

Synthesis of compounds with juvenile hormone activity; XXXI: Stereocontrolled synthesis of (+)-juvabione from a chiral sulfoxide

A stereocontrolled synthesis of (+)-juvabione is described. The key step is a regioselective lithiation of a chiral (E)-butenyl sulfoxide 5 followed by stereoselective 1,4-addition to cyclohex-2-en-1-one. The chiral sulfoxide 5 was prepared by employing a

Synthesis of (+)-Juvabione, a Compound with Juvenile Hormone Activity

(+)-Juvabione 1 was synthesized by employing (1R,4S,6S)-6-hydroxybicyclooctan-2-one 2 as a chiral source. (+)-Juvabione 1 shows juvenile hormone activity, and its racemate has been repeatedly synthesized.Optically active 1 was synthesized by Pawson

OCCURENCE OF EPIJUVABIONE-TYPE SESQUITERPENOIDS IN ABIES SACHALINENSIS

The wood of Abies sachalinensis from the Taisetsu mountain range of Japan afforded, in addition to 10 known compounds, seven new epijuvabione-type sesquiterpenoids, (+)-4'-dehydro-oxoepijuvabione, (-)-4'-dehydro-oxojuvabione, epijuvabienol ether, 5'-hydroxyepijuvabione, ar-dihydroxyepijuvabione, 3'-dehydroepijuvabi-5'-ol and 3'-isodihydroepitodomatuic acid.Their stereostructures were elucidated by chemical and spectral evidence. Key Word Index: Abies sachalinensis; Pinaceae; wood; epijuvabione anlogue; sesquiterpenoid.

SESQUITERPENOIDS RELATED TO JUVABIONE IN ABIES PINSAPO

From the acid fraction of the hexane extract of the wood of Abies pinsapo, four new sesquiterpenoids related to juvabione have been isolated: epitodomatuic acid, cis-dihydroepitodomatuic acid, 4'-dehydroepitodomatuic acid and 3'-dihydroepitodomatuic acid.

A Synthesis of the Juvabiols

Synthetic studies utilizing condensations of α-sulfinyl carbanions, have provided (+)-juvabiol and its analogous diastereoisomers.