80447-43-4

Upstream product

• 10458-14-7 (2R,5S)-menthone 
• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 
• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 

Downstream Products

• 80434-59-9 (1R,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde 
• 795281-04-8 2,2-Dimethyl-propionic acid (E)-(R)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-4-(2-trimethylsilanyl-ethoxymethoxy)-but-2-enyl ester 
• 795277-06-4 (E)-(R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-8-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-6-methyl-oct-7-en-3-one 
• 795281-05-9 2,2-Dimethyl-propionic acid (E)-(R)-4-benzyloxy-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-but-2-enyl ester 
• 795277-64-4 (E)-(R)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-7-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-5-methyl-hept-6-en-2-one 
• 795278-25-0 tert-Butyl-{(R)-2-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-2-methyl-hex-5-enyloxy}-dimethyl-silane 
• 616866-94-5 2,2-Dimethyl-propionic acid (E)-(S)-4-(tert-butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-but-2-enyl ester 
• 616866-96-7 2,2-Dimethyl-propionic acid (E)-(R)-4-(tert-butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-but-2-enyl ester 
• 616866-95-6 (E)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-but-2-en-1-ol 
• 616866-93-4 (E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-but-2-en-1-ol 

Relevant academic research and scientific papers

p-menthane-3-carboxaldehyde: A useful chiral auxiliary for the synthesis of chiral quaternary carbons of high enantiomeric purity

(+)- or (-)-p-Menthane-S-carboxaldehyde is made in two easy steps from (+)- or (-)-menthone, respectively. This auxiliary allows for the synthesis of carbonyl compounds bearing a α-chiral quaternary carbon. The flexibility, efficiency, and ease of use of

STEREOSELEKTIVE SYNTHESE UND STRUKTUR VON 1-(AMINO-(S)-METHYL)FERROCEN

A stereospecific multistage synthesis of 1-(amino-(S)-methyl)ferrocene (7) with the natural (-)-menthone as an educt is reported.The configuration of the product 7 is evaluated by way of an X-ray structure analysis.In the addition further analytical data including spectroscopic ones of 7 and its precursors 2, 4, and 6 are given.